Van Der Waals Phase Transition

In summary: This involves rearranging the given equation for T and using a limiting process for density at the critical point. The resulting equation shows that T and P are different for gas and liquid phases. To find the relationship between phase change and density, approach the critical temperature and make the pressure the same for both phases. This leads to the proportionality shown in equation 5.9. The Widom Insertion Method is discussed in more detail in the paper linked in the conversation.
  • #1
Diracobama2181
75
2
Homework Statement
Show that $$\rho_{gas}-\rho_{liquid}\propto |T_C-T|^\frac{1}{2}$$.
Relevant Equations
$$P=\frac{\rho RT}{1-\rho \beta}-\alpha \rho^2$$
Not sure where to actually start. Do I need to do a virial expansion? Any tips on on where to start would be greatly appreciated.
 
Physics news on Phys.org
  • #2
Start by writing down alpha and beta in terms of TC and PC.
 
  • #3
Rearrange the given equation for T. Now,at critical point density is infinite. So, use limiting process for density.
 
  • #4
Abhishek11235 said:
Rearrange the given equation for T. Now,at critical point density is infinite. So, use limiting process for density.
Would T and P be different for $$\rho_{gas}$$ and $$\rho_{liquid}$$?
Right now, after rearranging, I get
$$T=\frac{P-\rho \beta P+\alpha \rho^2-\alpha \beta \rho^3}{R\rho}$$
which gives
$$T=\frac{- \beta P+\alpha \rho-\alpha \beta \rho^2}{R}$$
when I let $$\rho$$ go to $$ \infty$$
 
Last edited:
  • #5
Diracobama2181 said:
which gives
$$T=\frac{- \beta P+\alpha \rho-\alpha \beta \rho^2}{R}$$
when I let $$\rho$$ go to $$ \infty$$

As it should(There is very exciting physical phenomenon related to this). Now you want to find relation between phase change and density. For this,you have to approach one temperature(The critical temperature)(Why?). Next,the pressure should be same(This should become clear if you P-T graph of phase change relationship)
 
  • #7
Diracobama2181 said:
Homework Statement:: Show that $$\rho_{gas}-\rho_{liquid}\propto |T_C-T|^\frac{1}{2}$$.
Homework Equations:: $$P=\frac{\rho RT}{1-\rho \beta}-\alpha \rho^2$$

Not sure where to actually start. Do I need to do a virial expansion? Any tips on on where to start would be greatly appreciated.
Use the Widom Insertion Method
 

1. What is the Van Der Waals Phase Transition?

The Van Der Waals Phase Transition is a phenomenon in which a substance undergoes a change in state under certain conditions. It involves the transition from a gas to a liquid state, and is characterized by a sudden increase in density and a decrease in volume.

2. What causes the Van Der Waals Phase Transition?

The Van Der Waals Phase Transition is caused by intermolecular forces between particles within a substance. These forces become stronger as the temperature decreases and the particles move closer together, resulting in the formation of a liquid state.

3. What is the significance of the Van Der Waals Phase Transition?

The Van Der Waals Phase Transition is significant in understanding the behavior of substances at different temperatures and pressures. It also has practical applications in fields such as chemistry, materials science, and engineering.

4. How is the Van Der Waals Phase Transition different from other phase transitions?

The Van Der Waals Phase Transition is different from other phase transitions, such as the solid to liquid transition, in that it does not involve a change in the molecular structure of the substance. Instead, it is a change in the arrangement and movement of particles.

5. Can the Van Der Waals Phase Transition be observed in everyday life?

Yes, the Van Der Waals Phase Transition can be observed in everyday life. For example, the condensation of water vapor on a cold surface is a type of Van Der Waals Phase Transition. Other examples include the formation of dew on grass in the early morning and the formation of clouds in the atmosphere.

Similar threads

  • Advanced Physics Homework Help
Replies
6
Views
2K
  • Advanced Physics Homework Help
Replies
1
Views
980
  • Advanced Physics Homework Help
Replies
7
Views
2K
  • Chemistry
Replies
2
Views
979
Replies
4
Views
208
  • Advanced Physics Homework Help
Replies
6
Views
3K
  • Advanced Physics Homework Help
Replies
23
Views
9K
  • Advanced Physics Homework Help
Replies
4
Views
3K
  • Introductory Physics Homework Help
Replies
2
Views
802
  • Advanced Physics Homework Help
Replies
6
Views
3K
Back
Top