X-Ray Diffraction Homework: Find Crystal Spacing

Instead, you can use the Debye-Scherrer equation: λ = 2dsinθwhere λ is the wavelength of the X-ray beam, d is the crystal spacing, and θ is the angle of diffraction. In this case, θ = 22 degrees and 35 degrees, and the known value of λ is 10^10m. By plugging in these values, you can solve for d, which will be the average crystal spacing in the powdered sample.
  • #1
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Homework Statement


An X Ray beam (wavelength 10^10m) is incident upon a sample of a powdered crystalline material. At a distance of 5m from the sample a flat detecting film has been placed. A pattern of 2 circles have been recorded on this film (radius 2cm and 3.5cm).

What crystal spacing does this pattern correspond to?


Homework Equations


I'm not sure but:

mλ = 2dsinθ

(The reason I am unsure as that is for solid crystals not powder)

The Attempt at a Solution



So far I ahve calculated the angles the circles are at to the beam:

tan θ = 2/5 so θ = 22 degrees

tan θ = 3.5/5 so θ = 35 degrees

Next I tried putting them both into the above equation trying to calculate d but that makes little sense to me.

Anyone able to help?
 
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  • #2
The equation you have uses the Bragg Diffraction principle which is valid for single crystal only. Since this is a powdered sample, the diffraction will be from many crystals in a random orientation. Hence, you cannot use the Bragg equation to find the crystal spacing.
 
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