X-Ray Diffraction: Explaining Visible Light Reflection

In summary, when x-rays interact with atoms, the electrons in the atom re-emit the x-radiation as a spherical wavefront due to the interaction, while visible light has a longer wavelength and behaves differently, following the laws of geometrical optics when interacting with matter.
  • #1
manofphysics
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"When a wavefront of X-rays strikes an atom, the electrons in that atom interact with the X-rays and immediately re-emit the X-radiation, normally without change of wavelength, and the X-radiation that is emitted by the atom is emitted as a spherical wavefront "

Now my question is : visible light is also an electromagnetic wave, but we only experience Reflection in a straight line(if the object is well polished)Why does the visible light also not produce spherical wavefronts after striking the electron on the surface of the polished object, instead of showing proper straight line reflection?

I know this may sound like a elementary concept to some, but still I would be grateful if someone could clear up this doubt.Thanks,
 
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  • #2
manofphysics said:
"When a wavefront of X-rays strikes an atom, the electrons in that atom interact with the X-rays and immediately re-emit the X-radiation, normally without change of wavelength, and the X-radiation that is emitted by the atom is emitted as a spherical wavefront "

Now my question is : visible light is also an electromagnetic wave, but we only experience Reflection in a straight line(if the object is well polished)Why does the visible light also not produce spherical wavefronts after striking the electron on the surface of the polished object, instead of showing proper straight line reflection?

I know this may sound like a elementary concept to some, but still I would be grateful if someone could clear up this doubt.Thanks,

Visible light has a very long wavelength compared to interatomic distances in a solid, so the interaction of visible light with a solid can be described using the macroscopic electrodynamics of continuous materials (as described, e.g., in the book by Landau and Lifgarbagez). For this case one can consider the system characterized entirely by the dielectric function [itex]\epsilon[/itex] or equivalently the index of refraction [itex]n[/itex].

The usual procedure of equating the (incident, reflected, and refracted) macroscopic electric fields at the boundry leads to the kinematic equations
[tex]
\sin(\theta_{\tt inc.})n_{\tt inc.}=\sin(\theta_{\tt reflect.})n_{\tt reflect.}=\sin(\theta_{\tt refract.})n_{\tt refract.}\;,
[/tex]
but, since the incident and reflected have the same index of refraction the incident and reflected waves make the same angle w.r.t. the normal which means that the light reflects off the mirror in just the way one believes from geometrical optics. The final equality in the above equation is, of course, Snell's law.

For x-rays the situation is entirely different since the wavelength of x-rays is about the same as the interatomic spacing or less and macroscopic electrodynamics does not apply. Thus we think about the x-rays interacting with each atom individually not en mass (i.e., macroscopically). So, when the x-ray polarizes the atom there will generally be different angular momentum components of emitted light due to the resulting wiggling of the atomic electrons, but often the zeroth (i.e., spherical) component dominates and this gives rise the the idea you have mentioned about spherical waves being emitted from the position of the atom.
 
  • #3


Thank you for your question. The difference in the behavior of X-rays and visible light when interacting with atoms is due to their different wavelengths. X-rays have much shorter wavelengths (in the range of 0.01-10 nanometers) compared to visible light (in the range of 400-700 nanometers). This means that X-rays have higher energy and can penetrate deeper into materials, while visible light is more easily reflected or absorbed by the surface of an object.

When visible light strikes an atom, the electrons in that atom interact with the light but do not immediately re-emit it as a spherical wavefront. Instead, they are excited to higher energy levels and then quickly return to their original state, releasing the energy as a new photon of visible light. This process is known as elastic scattering and results in the visible light being reflected in a straight line.

On the other hand, X-rays have enough energy to cause the electrons in an atom to be completely removed, resulting in a process called inelastic scattering. This means that the X-rays are not simply reflected in a straight line, but can also be scattered in different directions, resulting in a spherical wavefront.

In summary, the difference in the behavior of X-rays and visible light when interacting with atoms is due to their different energy levels and how they interact with the electrons in the atom. I hope this helps to clarify your doubt.
 

1. What is X-Ray Diffraction?

X-Ray Diffraction is a scientific technique used to analyze the structure of materials by measuring how X-rays scatter off of them. It is commonly used in fields such as crystallography, material science, and mineralogy.

2. How does X-Ray Diffraction work?

X-Ray Diffraction works by directing a beam of X-rays onto a sample and detecting the pattern of diffracted X-rays that results. This pattern is then analyzed to determine the arrangement of atoms or molecules in the sample.

3. What types of materials can be analyzed using X-Ray Diffraction?

X-Ray Diffraction can be used to analyze a wide range of materials, including crystals, powders, thin films, and even liquids. It is especially useful for studying materials with ordered structures, such as minerals and polymers.

4. How is X-Ray Diffraction different from visible light reflection?

X-Ray Diffraction and visible light reflection are both forms of scattering, but they differ in the size of the wavelengths used. X-rays have much shorter wavelengths than visible light, allowing them to interact with smaller features in a sample and provide more detailed information about its structure.

5. What are the practical applications of X-Ray Diffraction?

X-Ray Diffraction has many practical applications, including identifying unknown substances, determining the purity of a sample, and studying the properties of new materials. It is also commonly used in the pharmaceutical industry to analyze the structure of drugs and their interactions with other molecules.

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