Sources of errors on Determinating Faraday's Constant experiment

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SUMMARY

The discussion identifies three primary sources of error in the determination of Faraday's Constant during an electrochemical experiment using copper strips and a 0.1M CuSO4 solution. The greatest source of error is attributed to improperly drying the electrodes, which affects the weight measurement of the copper strips. Inaccurate measurements of time and current are also significant contributors, while contamination of glassware is deemed a minor concern. The steps outlined include weighing the copper strips, immersing them in the solution, and recording current readings over time.

PREREQUISITES
  • Understanding of electrochemical experiments
  • Familiarity with weighing techniques and precision measurement
  • Knowledge of current and voltage measurement using an ammeter
  • Basic principles of Faraday's laws of electrolysis
NEXT STEPS
  • Research best practices for drying electrodes in electrochemical experiments
  • Learn about accurate measurement techniques for time and current
  • Explore methods to minimize contamination in laboratory glassware
  • Study the implications of Faraday's laws on electrochemical calculations
USEFUL FOR

This discussion is beneficial for chemistry students, laboratory technicians, and researchers conducting electrochemical experiments who seek to improve the accuracy of their measurements and understand sources of error in their calculations.

david2120
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Give three sources of error in your calculation in Part B. Which of these contributions the greatest source of error? Explain.

In part B i did 6 steps in determination of Faraday's Constant.

1. I marked two copper strips (to distinguish them) and weigh them

2. Attach these to the alligator clips of your apparatus

3. Half fill a 150 ml beaker with 0.1M CuSO4 solution; insert the copper strips into the solution and begin timing.

4. Read the ammeter and record the value every thirty seconds for fifteen minutes.

5. Disconnect the alligator clips, allow the electrodes to sit for a minute, then rinse them. Allow to dry on a paper towel and reweigh.

6. Perform the appropriate calculations.


I believe that the greastest source of error is too rub the electrodes dry I think that would change your calculations on the weight of the copper strips.

second would be inaccurate measurements.

third would be contamination on glassware
 
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david2120 said:
I believe that the greastest source of error is too rub the electrodes dry I think that would change your calculations on the weight of the copper strips.
david2120 said:
second would be inaccurate measurements.
third would be contamination on glassware
"Inaccurate measurements" of what? Times and currents come readily to mind. "Contamination on glassware" is NOT a significant source. Actual current/voltage selected is one possible third source of error.
 

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