Verifying Equation: Calculating <E>,<x>,<p> in 1-D Box

  • Thread starter Thread starter ynuo
  • Start date Start date
Click For Summary
SUMMARY

The discussion focuses on calculating the expectation values , , and

for a particle in a one-dimensional box using the wave function Psi(x, t) = 1/sqrt(a) * [sin(2*pi*x/a)*e^(-i*E2*t/h_bar) + cos(3*pi*x/a)*e^(-i*E3*t/h_bar)]. The calculations involve integrating the wave function over the specified limits and applying the equations =Int[Psi_star*(i*h_bar*d/dt)*Psi, x=-a/2..a/2], =Int[Psi_star*(-i*h_bar*d/dx)*Psi, x=-a/2..a/2], and

=Int[Psi_star*x*Psi, x=-a/2..a/2]. The user encounters difficulties in proving the relation

=m*d/dt after substituting the energy values E2 and E3.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly wave functions.
  • Familiarity with expectation values in quantum mechanics.
  • Knowledge of integration techniques in calculus.
  • Proficiency in using LaTeX for mathematical expressions.
NEXT STEPS
  • Study the derivation of expectation values in quantum mechanics.
  • Learn about the properties of wave functions in one-dimensional potential wells.
  • Explore the relationship between momentum and position in quantum mechanics.
  • Practice using LaTeX for formatting complex equations and expressions.
USEFUL FOR

Students and professionals in physics, particularly those studying quantum mechanics, as well as educators looking to enhance their understanding of wave functions and expectation values.

ynuo
Messages
18
Reaction score
0

Homework Statement



Consider the wave function

Psi(x, t)=1/sqrt(a) * [sin(2*pi*x/a)*e^(-i*E2*t/h_bar) + cos(3*pi*x/a)*e^(-i*E3*t/h_bar)]

for the particle in the one-dimensional box.

a) Calculate the expectation values <E>, <x>, and <p>.
b) Show that <x> and <p> satisfy the relation <p>=m*d<x>/dt

Homework Equations



<E>=Int[Psi_star*(i*h_bar*d/dt)*Psi, x=-a/2..a/2]
<x>=Int[Psi_star*(-i*h_bar*d/dx)*Psi, x=-a/2..a/2]
<p>=Int[Psi_star*x*Psi, x=-a/2..a/2]

The Attempt at a Solution



a) <x>=Int[1/a*[sin(2*pi*x/a)*e^(i*E2*t/h_bar) + cos(3*pi*x/a)*e^
(i*E3*t/h_bar)]*x*[sin(2*pi*x/a)*e^(-i*E2*t/h_bar) + cos
(3*pi*x/a)*e^(-i*E3*t/h_bar)], x=-a/2..a/2]

After integration and simplification I get:

<x>=(-24*a/25*pi^2) * (e^(i(E3 - E2)t/h_bar)) + e^(i(E2-E3)t/h_bar)

And for <p>: <p>=Int[-i*h_bar/pi (sin(2*pi*x/a) * e^(i*E2*t/h_bar) +
cos(3*pi*x/a)*e^(i*E3*t/h_bar))*d/dx(sin(2*pi*x/a) * e^
(-i*E2*t/h_bar) + cos(3*pi*x/a)*e^(-i*E3*t/h_bar)),
x=-a/2..a/2]

After integration and simplification I get:

<p>=-i*h_bar/pi * [-4*a/(15*pi)*e^(i(E2-E3)t/h_bar) +
=3*a/(5*pi) * e^(i(E3-E2)t/h_bar)

After substituting E2=(2 * pi^2 * h_bar^2)/(m*a^2)
E3=9/2 * pi^2*h_bar^2/(m*a^2)

in <x> and <p> and applying m*d/dt to <x> I don't get
<p>=m*d<x>/dt

This is what I get for the RHS:

m*d<x>/dt=(-12/5)*i*h_bar/a * [e^(i((2.5*pi^2 * h_bar^2)/
(m*a^2)t/h_bar))-e^(-i((2.5*pi^2 * h_bar^2)/(m*a^2)
t/h_bar))

Can you please help. Thank you.
 
Physics news on Phys.org

Similar threads

  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 9 ·
Replies
9
Views
9K
  • · Replies 2 ·
Replies
2
Views
3K
Replies
5
Views
4K
Replies
12
Views
3K
Replies
16
Views
3K
Replies
27
Views
4K
Replies
24
Views
3K
Replies
7
Views
3K
  • · Replies 1 ·
Replies
1
Views
3K