Exponential Probability Density of Electron in 1D Potential Well

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Homework Help Overview

The discussion revolves around the probability density of an electron confined in a one-dimensional potential well, specifically addressing the condition where the energy of the electron is less than the potential energy barrier (V0). Participants are exploring the mathematical representation of the probability density function, which is expected to exhibit an exponential decay.

Discussion Character

  • Exploratory, Mathematical reasoning, Problem interpretation

Approaches and Questions Raised

  • Participants are attempting to apply the Schrödinger equation relevant to the scenario where the energy is less than the potential. Questions have been raised regarding the form of the solutions to the differential equation derived from the Schrödinger equation, and there is discussion about the correct representation of the wave function.

Discussion Status

The discussion is active, with participants providing guidance on the correct form of the equations and solutions. There is an ongoing exploration of the implications of the solutions to the Schrödinger equation, particularly in relation to the exponential form of the probability density function.

Contextual Notes

Participants are working under the assumption that the energy of the electron is less than the potential barrier, which influences the form of the wave function and the resulting probability density. There is a noted uncertainty regarding the next steps in deriving the probability density from the wave function.

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Homework Statement



An electron is in a 1 dimensional potential well. If the energy of the electron is < V0, show that the probability density P(x) for the electron falls exponentially:

P(x) = Aexp(-x/L)


I honestly have no clue, I've been trying all day to do this!
 
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You need to show us what you have been doing "all day", so that we can help to guide you in the right direction. What is the basic equation that you should be using to approach this problem? It has a catchy name...
 
[tex]\frac{-h bar^{2}}{2m}[/tex] [tex]\frac{d^2\psi}{dx^2}[/tex] = (E - V[tex]_{0}[/tex])[tex]\psi[/tex]

So that's the Schrödinger equation for when the energy is less than V0 I think...

Then to show the probability density...

P(x) = [tex]\int[/tex][tex]\psi[/tex](x)* [tex]\psi[/tex](x) = 1

I have no idea what to do next...
 
Ok, so the Schrödinger equation is psi''=k*psi, where k is a positive constant. What do the solutions to that equation look like?
 
The solutions are of the form

[tex]\psi[/tex] = Ae[tex]^{ikx}[/tex] + Be[tex]^{-ikx}[/tex]
 
Noooo. The k in psi''=k*psi is real and positive. How about A*exp(sqrt(k)*x)+B*exp(-sqrt(k)*x)?
 

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