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kuahji
Feb10-08, 07:13 PM
Ok, where am I going wrong on the following problem
What mass of water is in a solution that decreases in temperature from 25.0 to 20.0 when 2.00 g of NH4Cl are added? (The enthalpy of solution is 14.8 kJ/mol, and the specific heat of the solution is assumed to be 4.18 J/g·K.)

I set the problem up where the change in temp = q/(specific heat * mass of solution)

5K = 14800J/(4.18 J/g*K * (2g+xg)) Then I just solved for x & I keep getting around 700g. But the answer is suppose to be 24.5 g. Any ideas where my logic is breaking down?

opuktun
Feb11-08, 10:10 AM
place a negative sign in front of 5 K -___-;;

kindly note that change in temperature = final - initial...

do remember ok? :)

kuahji
Feb11-08, 02:57 PM
um... ok, that doesn't really change anything... if you look at my equation I already changed q to a postive 14800, whereas it would have been negative along with the change in temp, its a step I skipped showing. Which still doesn't help me, I'm still getting a little over 700g, & the answer is suppose to be 24.5. If I just change the 5 to a negative, I get negative grams :(. Again, it was already compensated for.

Bystander
Feb11-08, 04:03 PM
How many moles?

opuktun
Feb11-08, 04:57 PM
Oh hehheh, bystander spotted it ;p...

Kuahji, it should be 148000 J/mol rather than 148000 J

do a conservation of units, you should be able to work out the answer...

kuahji
Feb11-08, 08:31 PM
Yes, that work... for whatever reason I kept forgetting J/mol. Thanks again.