Boyant Force Questioni^^ Again?

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Discussion Overview

The discussion revolves around the concept of buoyant force, particularly in relation to hot air rising and the behavior of gas molecules with varying kinetic energies. Participants explore theoretical scenarios involving gas mixtures at different temperatures and the implications for buoyancy and thermodynamics.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • One participant expresses confusion about applying the concept of buoyant force to a system of gas molecules with higher kinetic energy, questioning how to define the system's volume and density.
  • Another participant suggests that a gas molecule with greater kinetic energy will not necessarily rise unless it is in a less dense environment, as it needs to interact with lower energy molecules and gravity to ascend.
  • Some participants argue that energetic gas molecules can push down colder ones, which may lead to a situation where the energetic molecules rise, but this is contested by others who question the mechanics of such interactions.
  • There is a discussion about the definition of density in a diffusing gas and how it relates to the behavior of gas molecules in a container.
  • One participant proposes that a hot molecule among cold ones will rise due to the statistical nature of their interactions, suggesting that the cold molecules form a new "floor" beneath the hot one.
  • Another participant introduces a scenario involving a box filled with air at different temperatures and discusses the potential effects of adding a high-energy molecule, questioning the significance of such perturbations in the context of buoyancy and thermodynamics.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the mechanics of buoyancy in relation to gas molecules with varying kinetic energies. Multiple competing views remain regarding the behavior of these molecules and the implications for thermodynamic laws.

Contextual Notes

Some participants note that the discussion involves complex interactions governed by the Navier-Stokes equations and that the processes are unsteady, which may complicate the application of thermodynamic laws to individual particles.

HungryChemist
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Boyant Force Questioni!^^ Again??

I already know that there were many posts relating to boyant force. The reason I know is because I read them all but still very confused so I need help from you guyz. T_T I am sorry for my bad English.

My problem is with the explanation that is most commonly given out for the question why hot air rise. For me it is hard to apply the concept of boyant force to the system which is the collection of particles with higher kinetic energy. Why? Imagine there is a container, half filled by hot air molecules. Now to work out this problem using Newton's law with boyant force concept, I need to have well defined system. To define system as the collection of particles with higher kinetic energy, I realize that I can't really define the volume of my system because the particles will swirl around in the certain region of box, will diffuse, and as guessed, will rise up. With out definite volume I can not give any means to its density. So I am stuck. I begin to doubt the concept of boyant force and density difference is not really explaning the question without skipping large step. Can somebody help me to understand?

For all that is said, I have two specific question.

Imagine we have a cubic container composed of gas. Let's say that there are many many gas molecules with low temperature. If we place the same gas molecule(Only one of it!) but with greater kinetic energy and release it from the very bottom of the container, will that one gas molecule rise up?

My another question is this...

Imagine there is a cubic box. Box is half filled with gas with higher kinetic energy and half filled with lower kinetic energy. Initially hotter gas molecules and cold gas molecules are positioned through out the space proportionally. What I mean is...hmmmmm...the density of number of molecules per volume of space is constant through the region that is bounded by the cubic box. Now, do you think the gas molecules with higher kinetic energy will begin to rise? (If so, isn'it violating the law's of thermodynamics?? decreasing the entropy?)

Excuse me if I am not so clear in terms and definitions.
 
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HungryChemist said:
Imagine we have a cubic container composed of gas. Let's say that there are many many gas molecules with low temperature. If we place the same gas molecule(Only one of it!) but with greater kinetic energy and release it from the very bottom of the container, will that one gas molecule rise up?.

It has energy, and thus speed, so it will bounce off container walls. But not nessarily rise. It needs to be with lower energy molecules and gravity to rise. The low energy molecules don't take so much space, so they are denser, and thus heavier as a whole. The energetic ones go where there is room, upwards.

HungryChemist said:
Imagine there is a cubic box. Box is half filled with gas with higher kinetic energy and half filled with lower kinetic energy. Initially hotter gas molecules and cold gas molecules are positioned through out the space proportionally. What I mean is...hmmmmm...the density of number of molecules per volume of space is constant throught the region that is bounded by the cubic box. Now, do you think the gas molecules with higher kinetic energy will begin to rise? (If so, isn'it violating the law's of thermodynamics?? decreasing the entropy?)

The energetic ones push away the cold ones, which fall (or "Plinko") to the ground. An energetic one bounces off higher in than a cold one. The cold ones who fall down don't bounce back up as much.
 
Gonzolo said:
It has energy, and thus speed, so it will bounce off container walls. But not nessarily rise. It needs to be with lower energy molecules and gravity to rise. The low energy molecules don't take so much space, so they are denser, and thus heavier as a whole. The energetic ones go where there is room, upwards..

When you say something is denser than the other, I really get lost. How would you define a density of diffusing gas?

The one gas molecules with high kinetic energy is 'with' lower energy molecules which occupies most of the region of the cubic box. And sorry if didn't specifically mentioned, but the gravity is acting here too! So then, as you said the single molecule will go up?



Gonzolo said:
The energetic ones push away the cold ones, which fall (or "Plinko") to the ground. An energetic one bounces off higher in than a cold one. The cold ones who fall down don't bounce back up as much.

'an energetic one bounces off higher in than a cold one' doesn't make me to understand why the energetic one should rise. Cuz I can argue that the energetic one can bounces back again and drops down in the box further than the cold one.
 
Density of a diffusing gas : [tex]\rho_{gas x}(x,y,z,t)[/tex] But we don't need that to understand, so let's forget it for now. I find it easier to understand imagining a gas as rubber balls anyway.

Having one hot molecule among many cold ones, yes, the hot one will rise. This is because when any cold one go down, it doesn't come up again as high as the hot one. If you wait long enough the end result would be a new "floor" of cold molecules with the hot one bouncing on top of them.

Imagine those pools of plastic balls for kids. Those are all "cold molecule". If one of them is shaking a lot for an imaginary reason, it will move around until after sometime, it will by pure chance go on top. Once it is there, it won't be able to go back down, because the cold balls will have formed a new "floor" underneath.

"Cuz I can argue that the energetic one can bounces back again and drops down in the box further than the cold one."

No you can't! There is a floor! Take a hundred balls boucing on the floor, half of which are more energetic (bounce higher) than the other. The average height of the energetic ones is greater! That's all! The energetic balls are statistically "risen" relative to the others.
 
HungryChemist said:
For all that is said, I have two specific question.

Imagine we have a cubic container composed of gas. Let's say that there are many many gas molecules with low temperature. If we place the same gas molecule(Only one of it!) but with greater kinetic energy and release it from the very bottom of the container, will that one gas molecule rise up?

My another question is this...

Imagine there is a cubic box. Box is half filled with gas with higher kinetic energy and half filled with lower kinetic energy. Initially hotter gas molecules and cold gas molecules are positioned through out the space proportionally. What I mean is...hmmmmm...the density of number of molecules per volume of space is constant through the region that is bounded by the cubic box. Now, do you think the gas molecules with higher kinetic energy will begin to rise? (If so, isn'it violating the law's of thermodynamics?? decreasing the entropy?)

.

This is my version:

First question: If you have a box filled with air molecules at 200K and you add one molecule with a kinetic energy equivalent to 1000K , perhaps this molecule crash into others, slowing down his kinetic energy and creating certain number of molecules (certain mass) that would have instantaneously less average density than the sorrounding ones. The gravity forces would act over the molecules above them. But I think that this effect has no sense with such small perturbation. Perhaps times involved in energy dissipation are much smaller than those involved in the macroscopic mass movement (bouyancy forces or convection).

Second question: this is not violating any thermodynamic law. The movement of the air molecules is an unsteady process. Second law of thermodynamic is applied to each one fluid particle. I mean, the diffussing and convective process we are talking about is governed by the Navier-Stokes equations. Surely, each molecule transports certain amount of entropy to other box parts, due to convective inertia, heat transfer, and viscosity (Rayleigh) dissipation. But the total variation in time (integrated at all volume) would be increasing in each instant of time. As t--->infinite, you could apply the classical 2nd thermodynamic law. The gas will be reached the complete steady state, probably having a higher average temperature, and if the boundaries are adiabatic, the system entropy would be increased.

I hope this can help you to unpuzzle your ideas.
 
HungryChemist said:
I already know that there were many posts relating to boyant force. The reason I know is because I read them all but still very confused so I need help from you guyz. T_T I am sorry for my bad English.

My problem is with the explanation that is most commonly given out for the question why hot air rise. For me it is hard to apply the concept of boyant force to the system which is the collection of particles with higher kinetic energy. Why? Imagine there is a container, half filled by hot air molecules. Now to work out this problem using Newton's law with boyant force concept, I need to have well defined system. To define system as the collection of particles with higher kinetic energy, I realize that I can't really define the volume of my system because the particles will swirl around in the certain region of box, will diffuse, and as guessed, will rise up. With out definite volume I can not give any means to its density. So I am stuck. I begin to doubt the concept of boyant force and density difference is not really explaning the question without skipping large step. Can somebody help me to understand?

For all that is said, I have two specific question.

Imagine we have a cubic container composed of gas. Let's say that there are many many gas molecules with low temperature. If we place the same gas molecule(Only one of it!) but with greater kinetic energy and release it from the very bottom of the container, will that one gas molecule rise up?

My another question is this...

Imagine there is a cubic box. Box is half filled with gas with higher kinetic energy and half filled with lower kinetic energy. Initially hotter gas molecules and cold gas molecules are positioned through out the space proportionally. What I mean is...hmmmmm...the density of number of molecules per volume of space is constant through the region that is bounded by the cubic box. Now, do you think the gas molecules with higher kinetic energy will begin to rise? (If so, isn'it violating the law's of thermodynamics?? decreasing the entropy?)

Excuse me if I am not so clear in terms and definitions.

No molecule is going to go very far. It will bump into another and some of the energetic molecule's energy gets transferred to the low energy molecule. Eventually, if it's a closed system, you reach equilibrium where all of the molecules have the same energy (and temperature). If the distribution were uniform throughout the box, the energy of the molecules would quickly stablize to a common level, as well.

Recalling your post in one of the other threads, I think your problem is this:

In an open system, the molecule can go up, down, sideways, whatever. A high energy molecule will go further than a low energy molecule in which ever direction it randomly travels. So why are there more of them at higher levels.

Because the system is only open on top and a high energy molecule won't really move much further than a low energy molecule. Both will run into another molecule. The high energy molecule hits neighboring molecules with more energy.

You can only push 'down' so far, so the density is greater in the 'down' direction, meaning you hit another molecule quicker when you're heading down.

You can push 'up' as far as you want. The top just expands further out. Any given molecule can only travel so far before it hits another molecule, but the high energy molecules tend towards higher altitudes than the low energy molecules.
 

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