First and Second Law of Thermodynamics

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Homework Help Overview

The discussion revolves around the behavior of an ideal gas in a thermally isolated cylinder with a movable piston, focusing on the implications of the first and second laws of thermodynamics. Participants explore concepts such as internal energy, heat transfer, work done by the gas, and the nature of the process involved.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants question whether the internal energy of the gas remains constant when heat is added, referencing the conservation of energy.
  • There are inquiries about the implications of the second law of thermodynamics regarding the conversion of heat into work.
  • Some participants discuss the relationship between the area of the piston and the work done by the gas, raising questions about the independence of work from piston area.
  • References to Joule's experiment and the ideal gas law are made to support reasoning about the system's behavior.

Discussion Status

The discussion is active, with various interpretations being explored regarding the thermodynamic principles at play. Some participants provide insights into the relationships between pressure, volume, and work, while others question the assumptions made about the system's energy dynamics. There is no explicit consensus, but productive dialogue is evident.

Contextual Notes

The problem is framed within the constraints of a thermally isolated system, and participants are navigating the implications of this setup on energy conservation and thermodynamic laws.

Soaring Crane
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An ideal gas is confined within a thermally isolated cylinder. It consists of N atoms initially at a pressure of p_0. A movable piston seals the right end of the cylinder. A given amount of heat Q is slowly added to the gas, while the piston allows the gas to expand in such a way that the gas's temperature remains constant at T_0.

Is the internal energy of the gas the same before and after Q is added?
Is this true since it has to follow the law of the conservation of energy?

Does the second law of thermodynamics forbid converting all of the absorbed heat Q into work done by the piston?
Is the movable piston a cycle? I think it is, so it must follow the second law?

Is the total work done by the gas independent of the area of the piston?

Well, the total work is dW = p*dV, and since V = A*h, then work is dependent and not independent?
 
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Soaring Crane said:
An ideal gas is confined within a thermally isolated cylinder. It consists of N atoms initially at a pressure of p_0. A movable piston seals the right end of the cylinder. A given amount of heat Q is slowly added to the gas, while the piston allows the gas to expand in such a way that the gas's temperature remains constant at T_0.

Is the internal energy of the gas the same before and after Q is added?
Is this true since it has to follow the law of the conservation of energy?

What does James Prescott Joule's experiment tell u about ideal gases...??

Soaring Crane said:
Does the second law of thermodynamics forbid converting all of the absorbed heat Q into work done by the piston?
Is the movable piston a cycle?

What??What kind of the process is described in the problem...?

Soaring Crane said:
Is the total work done by the gas independent of the area of the piston?

Well, the total work is dW = p*dV, and since V = A*h, then work is dependent and not independent?

Think again...What is changing in the volume...??The area or the "length" of the tube (improperly said)?

Daniel.
 
Soaring Crane said:
An ideal gas is confined within a thermally isolated cylinder. It consists of N atoms initially at a pressure of p_0. A movable piston seals the right end of the cylinder. A given amount of heat Q is slowly added to the gas, while the piston allows the gas to expand in such a way that the gas's temperature remains constant at T_0.

Is the internal energy of the gas the same before and after Q is added?
Is this true since it has to follow the law of the conservation of energy?
Use the Ideal gas law: PV=nRT = internal energy of the gas. If T and n do not change then PV cannot change. (Since V increases, P must decrease as 1/V).

Does the second law of thermodynamics forbid converting all of the absorbed heat Q into work done by the piston?
Is the movable piston a cycle? I think it is, so it must follow the second law?
This is an interesting question. Since the container is thermally isolated, no heat can escape. The first law says that [itex]\Delta Q = \Delta U + \Delta W[/itex]. Since [itex]\Delta U = \Delta PV = nR\Delta T = 0[/itex] in this process, it would appear that [itex]\Delta Q = \Delta W[/itex] where [itex]\Delta W[/itex] is the work done by the system. Since this would violate the second law, we can conclude that this is not the entire system. I think the second law tells us that there had to be an external source of energy, in addition to the added heat, to move the piston and expand the gas. The heat alone could not do the work of moving the piston.

Is the total work done by the gas independent of the area of the piston?

Well, the total work is dW = p*dV, and since V = A*h, then work is dependent and not independent?
I don't think so. The total work done by the gas is:

[tex]\int_{V_i}^{V_f} PdV = \int_{V_i}^{V_f} \frac{dV}{V} = ln(\frac{V_i}{V_f})[/tex]

It is independent of the area of the piston.

AM
 
Soaring Crane said:
Is the total work done by the gas independent of the area of the piston?

Well, the total work is dW = p*dV, and since V = A*h, then work is dependent and not independent?

While it is true that V = A*h, it is also true that p = F/A. So the A's cancel each other out and the work done is therefore independent of the area. :smile:
 

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