Strange derivation: Statistical thermodynamics

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SUMMARY

The discussion centers on a derivation in statistical thermodynamics from the book "Thermal Physics" by Kittel & Kroemer. The user, Declan, struggles with understanding the transition from one equation to another involving Helmholtz free energy (F), partition function (Z), average energy (U), fundamental temperature (τ), and entropy (σ). Daniel provides a solution by suggesting the use of the product rule for derivatives on the expression U = -τ² ∂(F/τ)/∂τ to revert to the previous equation. He also recommends Greiner's "Thermodynamics & Statistical Physics" for clearer explanations.

PREREQUISITES
  • Understanding of Helmholtz free energy (F)
  • Familiarity with partition function (Z)
  • Knowledge of average energy (U) in statistical mechanics
  • Proficiency in calculus, specifically product rule for derivatives
NEXT STEPS
  • Study the product rule for derivatives in calculus
  • Explore Greiner's "Thermodynamics & Statistical Physics" for detailed derivations
  • Research the relationship between Helmholtz free energy and entropy
  • Learn about the partition function and its applications in statistical mechanics
USEFUL FOR

Students and professionals in physics, particularly those studying statistical thermodynamics, as well as anyone seeking to deepen their understanding of thermodynamic equations and their derivations.

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This isn't a homework question. I'm studying this from a book (Thermal Physics by Kittel & Kroemer) currently. Up til now I've had no problem following it. There's one derivation that's got me a little stumped however. I had thought my calculus was proficient enough, but I'm just not seeing something here and it's very frustrating. Y'know how it is when you just can't let yourself continue until you get past this tiny hurdle

Anyway here it is scanned from the book:
http://www.maths.tcd.ie/~cockburd/thermo.gif

The equation circled is the bit I'm having trouble with, I see where he's going with putting it in that form but I can't see how he got that equation from the one immedietly prior..

by the way:
F is helmholtz free energy,
Z is the partition function,
U is the average energy of the ensemble,
tau is the fundamental temperature and
sigma is the entropy

Thanks
Declan
 
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Quick reply
Take this expression
[tex] U=-\tau^2 \frac{\partial(F/ \tau)}{\partial \tau}[/tex]
use the product rule for derivatives. And you'll get back to the prior equation
 
You could use Greiner's text on Thermodynamics & Statistical Physics. It's much more clear and the calculations are detailed.

Daniel.
 

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