Understanding the Role of Viscosity and Elasticity in Dissipative Thermodynamics

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SUMMARY

The discussion centers on the application of Onsager's relations in the context of dissipative thermodynamics, specifically regarding the relationship between viscosity and elasticity in systems like dashpots and springs. The equation derived from the principles states that the sum of the derivatives of free energy and dissipation function equals the generalized force. The user successfully applies this to a dashpot, confirming Newtonian viscosity, but encounters confusion when extending the concept to a series system involving both a spring and a dashpot, particularly regarding the interpretation of the generalized force for the dashpot.

PREREQUISITES
  • Understanding of Onsager's relations in thermodynamics
  • Familiarity with the concepts of free energy and dissipation function
  • Knowledge of Newtonian viscosity and its mathematical representation
  • Basic principles of mechanical systems involving springs and dashpots
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  • Research the mathematical formulation of Onsager's relations in dissipative systems
  • Study the relationship between elasticity and viscosity in mechanical systems
  • Explore the dynamics of systems involving multiple components, such as springs and dashpots in series
  • Learn about generalized forces in the context of thermodynamic systems
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Students and professionals in physics and engineering, particularly those focusing on thermodynamics, mechanical systems, and material science, will benefit from this discussion.

muzialis
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∂Hello there,

I am trying to understand the basics of thermodynamics of dissipative systems.
In the attached paper equation (2.13) is derived using the concpt of free-energy and Onsager's relations

It says that, restricting to only one generalized coordinate

∂V / ∂q + ∂D / ∂q' = Q

V being the free energy, D the dissipation function as defined by Onsager's principle, Q the generalized force associated to the generalized coordinate q, and the apex deoting differentiation wit respect to time.

Trying to make sense, I applied to a one-dimensional dissipative sisyem, a dashpot.

Indeed, for a dashpot V = 0 identically, so the equation suggests (D defined as D = 0.5 b q'^2)

b q' = Q

which makes perfect sense (Newtonian viscosity).

If I try to do the same with a spring and dashpot in series, having q1 and q2 as coordinates representing the extension of the spring and the dashpot, I end up with a system ,


∂V / ∂q_1 + ∂D / ∂q'_1 = Q_1
∂V / ∂q_2 + ∂D / ∂q'_2 = Q_2

The first makes perfect sense, expressing the fact the force in the spring equals the applied force.
The second should say the same for the dashpot, but I struggle to understand what Q_2 is. Should be a force conjugate to the displacement of the dashpot, but the dashpot react to an applied rate, not to an applied displacement.

Where am I going wrong?

Thanks
 

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Did you ever figure this out? I'm guessing from the title of the link you gave that there is both viscosity and elasticity involved. Elasticity is the reaction to the applied displacement, viscosity to the applied rate of displacement.
 

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