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Astronuc
#2
Feb5-12, 06:01 AM
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Assuming that PuO2 is stoichiometric, the ratio O/Pu = 2. That's a simple chemical balance. There might be a surplus or deficiency of O depending on how the material is fabricated, e.g., reducing or oxidizing environment. But O/M is usually well controlled and probably on the order of 2 +/- 0.002.

Note that 94-Pu-234 decays by alpha emission to 92-U-234 (also formed from Th-234 following two successive beta decays), but U likes to form UO2 as well, and ThO2 is also likely.
http://hyperphysics.phy-astr.gsu.edu...radser.html#c3


Now if the measured density is greater than 100% theoretical density (of stoichiometric PuO2), then there is likely a deficiency of O. If the density is less than 100% theoretical, then there is a possibility of an excess of O, or there is some porosity, or the metal is not entirely Pu.