Fresnel reflection and total internal reflection are related phenomena that occur at the semiconductor/air interface of LEDs. Fresnel reflection happens due to impedance and refractive index discontinuities at a single interface, while total internal reflection involves two interfaces that reflect light constructively or destructively. Both types of reflection impact the efficiency of LED light output, but neither can achieve complete light extraction. Additionally, the interface between epoxy or plastic and air also plays a role in light transmission. Understanding these concepts is crucial for optimizing LED performance.