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Free Electron

 
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Mar2-08, 10:06 PM   #1
 

Free Electron


What is the justification behind tight-binding, nearly free electron drude model, to assume electrons as non-interacting? Because it is clearly not the case when considering coloumbic interactions, why can these models do this? Coloumbic interactions are strong so I wouldn't consider them to be idealized.

Or why is density functional theory valid? How is it still valid by expressing things in terms of its electron density while neglecting couloumbic interactions?
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Mar3-08, 12:21 AM   #2
 
Nevermind I understand now.
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