The Kuratowski definition of an ordered pair is expressed as (a,b) = {{a},{a,b}}, which ensures that the order of elements matters. This definition implies that (a,b) = (c,d) if and only if a=c and b=d, focusing on the property rather than the nature of ordered pairs. The distinction between sets like {a,b} and {{a},{a,b}} is crucial, as the latter maintains the order of elements, while the former does not. The discussion clarifies that the set-theoretic definition effectively captures the concept of ordered pairs. Understanding this definition is essential for grasping the foundational aspects of set theory.