Understanding Heat: Is it Just Kinetic Energy or Also Electromagnetic Radiation?

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Discussion Overview

The discussion revolves around the nature of heat, exploring whether it is solely kinetic energy associated with the motion of particles or if it also encompasses electromagnetic radiation, particularly infrared radiation. Participants examine the definitions and mechanisms of heat transfer, including conduction, convection, and radiation, while considering the implications of temperature and molecular interactions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants assert that heat is primarily understood as kinetic energy from the vibration of particles, while others introduce the idea that heat may also be a form of electromagnetic radiation.
  • Infrared radiation is identified as the EM radiation associated with heat, with specific wavelengths mentioned.
  • There is speculation about the relationship between molecular collisions and the emission of infrared radiation, suggesting that both translational vibrations and electronic level changes may occur.
  • Some participants express uncertainty about the definition of "heat," questioning whether it is a clearly defined concept.
  • Heat is described as the energy that flows between systems due to temperature differences, but participants note that it is not strictly limited to infrared radiation.
  • Concerns are raised about whether all molecules emit infrared radiation at all temperatures, with some questioning the generalization of this claim.
  • Participants discuss the possibility of heat transfer occurring without photon emission, particularly in the context of heat conduction through molecular collisions.
  • There is a consideration of low-temperature systems and their relationship to infrared radiation and heat transfer mechanisms.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the nature of heat, with multiple competing views remaining regarding its definition and the role of electromagnetic radiation in heat transfer.

Contextual Notes

Participants highlight limitations in definitions and the complexity of heat transfer mechanisms, noting that the relationship between kinetic energy, molecular vibrations, and electromagnetic radiation is not fully resolved.

Gerinski
I am familiar with the usual concept that heat is kinetic energy (the vibration of matter particles) but I also read that heat is one of the faces of electromagnetic radiation, such as visible light, radiowaves or x rays.

Is it correct?
Is it actually both? (e.g. EM radiation just a side effect of the kinetical movement ? and probably able to cause kinetical movement again on the matter absorbing it?) if really EM radiation, in which length of the spectrum?
 
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Infrared is the EM radiation associated with "heat". This is includes wavelengths from around 10-2m to 10-6m.

I will speculate that molecular collisions with energy of this wavelength induces translational vibrations as much as it does electronic level changes.
 
Integral said:
Infrared is the EM radiation associated with "heat".

Thanks Integral.
Do I get some strange feeling by the fact that you wrote "heat" between quotes ? :-)
As you can guess from my original question, it was about understanding clearly what heat is.
The fact that you write "heat" between quotes makes me feel that even for you there's something not so clearly defined about what is meant by "heat" ?
 
Heat is the energy that flows between two systems (as a result of temperature differences).
 
As Integral explained, when molecules vibrate [which they always do] they emit infrared radiation [IR]. If you rapidly drag your finger across a smooth board, the molecules of your finger collide with molecules of the board imparting kinetic energy to the molecules of both surfaces. This causes them to vibrate more rapidly and emit higher frequency IR [and your finger feels hot]. If you took a picture using IR film, the hot spot on your finger would look bright and you would see a bright streak on the surface where your finger crossed it [although not as bright as your finger].
 
Chronos said:
As Integral explained, when molecules vibrate [which they always do] they emit infrared radiation [IR]. If you rapidly drag your finger across a smooth board, the molecules of your finger collide with molecules of the board imparting kinetic energy to the molecules of both surfaces. This causes them to vibrate more rapidly and emit higher frequency IR [and your finger feels hot]. If you took a picture using IR film, the hot spot on your finger would look bright and you would see a bright streak on the surface where your finger crossed it [although not as bright as your finger].

Are you saying that ALL molecules at ALL temperatures emit IR, or is this just a generalisation? I've often wondered...
 
"heat" is in quotation, perhaps because what we typically call heat is when our own temperature nerves are stimulated up to our brain.

Heat transfer theory will say that heat flows three ways : conduction, convection and radiation. If it is strictly radiation, there is now doubt that we speak of IR radiation. (other radiations can indirectly cause heat by causing IR.)

Inside matter (a metal or plastic), "heat" is a combination of IR radiation, vibrating molecules, and/or flowing electrons. Generally speaking, you might define heat as a flow of energy within the IR-range of oscillations (whether it is particle kinetic energy or radiation). IR radiation is always in the picture, but energetic particle cannot be ignored.
 
I quoted heat because it is easily misused and wanted to make clear that I was using the term loosely and not in the formal sense. Thus I was referring to that sensation we have in the palms of our hands when we hold them in front of the fire. Notice that in the formally correct definition given by Sirus there is no mention of wavelength, so heat is more general then infrared radiation. Infrared is the band of radiation which produces a sense of warmth to our nervous system. The heat would be the energy which is transferred from the source to our hands.

Heat will flow when any 2 systems in thermal contact are at different temperatures. It is not necessarily infrared in nature.
 
Adrian Baker said:
Are you saying that ALL molecules at ALL temperatures emit IR, or is this just a generalisation? I've often wondered...
Yes. I may, however, be mistaken and need a refresher course. I would, however, pose this question Can heat [energy] be exchanged between molecules without photons being emitted? If this is true, the black body spectrum of a mass must not be reliable indicator of its temperature.
 
  • #10
Integral said:
Heat will flow when any 2 systems in thermal contact are at different temperatures. It is not necessarily infrared in nature.

It is possible to talk about heat (and even create an entire heat conduction theory) without referring to IR radiation, but at the atomic level, I have not been able to think of a case where no IR would be involved in the last 5 minutes.
 
  • #11
Gonzolo said:
It is possible to talk about heat (and even create an entire heat conduction theory) without referring to IR radiation, but at the atomic level, I have not been able to think of a case where no IR would be involved in the last 5 minutes.
Even in a system of only heat conduction?

How about a very low temperature system where the total system energy is comparable to the energy of infrared,... is this even possible?
 
  • #12
Having completed refresher training, Integral is correct. Heat conduction is achieved without any photon exchanges, it is a kinetic transfer of energy through molecular collisions. IR is still emitted, but, that is not the heat transfer mechanism for conduction.
 
  • #13
If a system is so cold as to not radiate IR at all... well the cosmic background is I believe microwaves, and this is associated to 2-3 K. Yah, I guess, but that's pretty cold. Perhaps people use radio and microwave to "heat up" superfluids in small increments. Do they call it "heat" though?

I'll agree with Chronos, and thank him for confirming that IR is at least emitted. (if temperature is sufficiently high I suppose, i.e. above a few Kelvins)
 
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