Recent content by MatthiasS

Thanks aa lot for your answer! Yes, I was thinking about a hypothetical situation in which we have the same red/ox potential, but different rate constants. The reason for my question is that I am interested on how a thin surface layer (sufficiently thin to allow for electron tunneling) affects...

Hello together, my name is Matthias and I am new to the PF :) I am currently a PhD student in Applied Physics, and am working on functional electrodes (metallic and semiconducting) for novel biosensing applications. I just stumbled across PF, and thought it would be a great opportunity to...

Hi there, I am currently studying charge transfer reactions between metallic electrodes and redox couples in aqueous electrolytes (in a diffusion limited system), and I was wondering about the influence of the rate constant on the reduction/oxidation peak maximum. Typically, it is assumed that...