Recent content by ReidMerrill

  1. ReidMerrill

    2nd order ODE: modeling a spring

    So the equation would be 3x'' + 1x' + 6x =0 ?
  2. ReidMerrill

    2nd order ODE: modeling a spring

    Suppose a spring with spring constant 6N/m is horizontal and has one end attached to the wall and the other end attached to a 3 kg mass. Suppose the friction/damping constant is 1 N s/m Set up a differential equation that describes this system with x denoting displacement of the mass from...
  3. ReidMerrill

    How can I prepare a 0.1M NaOAc buffer at pH 5 using titration?

    I did some Google snooping and apparently the pH of a 0.1M solution of acetic acid is 2.88. In that case, how do I raise the pH without lowering the molarity?
  4. ReidMerrill

    How can I prepare a 0.1M NaOAc buffer at pH 5 using titration?

    For a lab I need to create a 0.1M solution of NaOAc buffer at pH 5 It's been a while since I worked with buffers. I'm struggling to find a way to get both the proper morality and proper pH. My first though was to create a 0.2M solution of acetic acid and titrate it to pH 5 using sodium...
  5. ReidMerrill

    Predicting Bond Enthalpy Trends for Atom-Hydrogen Bonds

    I just wondered if there was supposed to be a trend since they don't appear to follow any pattern.
  6. ReidMerrill

    Predicting Bond Enthalpy Trends for Atom-Hydrogen Bonds

    Is there a period trend for bond enthalpy? Specifically Atom-Hydrogen bonds. Need to find a trend in predicting the bond enthalpy of several atom-hydrogen bonds I calculated using gaussian. Any help would be appreciated, thanks!
  7. ReidMerrill

    Hydrogen bonds and binding energy question

    I'm doing a computational lab about binding energy and comparing different methods of solvation. What does positive and negative binding energy signify? Half of the places I look say the more positive the binding energy the stronger the interaction between the molecules. Other places say the...
  8. ReidMerrill

    Magnetic Susceptibility and Unpaired electrons

    1.6205 is the ppm. That's what the lab manual says to do. EDIT: I see. the ppm x 400 MHz= Hz. I wasn't reading carefully. I'll see if this fixes things
  9. ReidMerrill

    Magnetic Susceptibility and Unpaired electrons

    Homework Statement I'm am trying to find out the magnetic susceptibility,XM in order to calculate the number of unpaired electrons in Mn(acac)3 via the Evans Method Homework Equations XM = (477) Δv/(Qv1C) XM= X'm+ XM(metal)+ XM (ligands) Where X'M is the magnetic susceptibilty of just the...
  10. ReidMerrill

    IR active vibrations and point groups

    The hydrogens on the two carbons and on the nitrogen are not in the plane.
  11. ReidMerrill

    IR active vibrations and point groups

    Oh yeah that rings a bell. For the signma in the place of the paper what would it be since all of the atoms will go from x to -x and y to -y while Z stays the same. Would it be -19+-19+19 (if you consider all of the atoms?) or -1+-1+1
  12. ReidMerrill

    IR active vibrations and point groups

    I had σv as the plane in the page and σv' as the one perpendicular to the page. I don't think that should make a difference thought. I'm not sure what the contributions thing is. I was following along with a video of someone doing the same process but with water. And I totally forgot tho...
  13. ReidMerrill

    IR active vibrations and point groups

    Homework Statement In lab we synthesised cis and trans copper glycine and we have to use IR to differentiate the two so we have to figure out the number of IR active vibrations for each complex. It's been a year since I did anything with point groups so I'm not sure if I did it right. Homework...
  14. ReidMerrill

    Ligand Field Strength and UV absorbance

    Thanks! I took the lecture for this lab class last year so I forgot about that. That explains why the peak absorption shifts to lower wavelengths as more Cl is displaced by water.
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