I do not know what range automotive O2 sensors operate in.
You need to keep your O2 content below 2% as far as I know, to stay in a safe range. Our sensors ran in contact with the gas stream itself, sampling 2-5 cfh. fairly simple concept: sensor- meter-alarm. The high oxygen alarm needs to be wired to a kill switch for the whole enterprise. With enough compression and some oxygen you can make an explosion just like in a diesel engine, but it will probably be a one-stroke occurrence. With all that being said and with the caveat that you will die if you try this, I once loaned a leaky 50 year old one cylinder air compressor to a friend with a gas well that was not producing enough to supply his house. He hooked the intake of the compressor to the output of the well and the output of the compressor tank to his household supply line and turned it on. That old thing still had enough ring seal left to pull a slight vacuum on his gas well and send about 30 psi to his house. He ran it that way all winter and then hauled the compressor back to me. I will point out that the gas well was a good ways from the house, fortunately.