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loadsy
Nov4-06, 07:21 PM
Hey I've just been working on a chemistry lab lately in my chemistry course, and one of the problems on the lab write-up asks to:

Write the rate law for the following reaction, if it were to occur through a single-step mechanism.
2I^-(aq) + S2O8^2-(aq) -> 2SO4^2-(aq) + I2(aq)

Now since it is asking to write it as a single-step mechanism I would assume there is only one step needed.

Now in the lab it has given us this formula:

rate = -(delta[S2O8^-2])/(delta t) = -(1/2)(delta )/(delta t) = (1/2)(delta[SO4^2-])/(delta t) = (delta[I2])/(delta t)

So could you not just say the only step needed is:
-(delta[S2O8^-2])/(delta t) = (delta[I2])/(delta t)

Then for the second part to the question it asks "[I]By examination of the experimentally determined rate law, explain whether this reaction does in fact proceed through a single-step mechanism. Explain."

Any help on this problem would be great, thanks.

GCT
Nov5-06, 03:43 PM
The rate law would be

rate=k(forward)[I-]^2[S2O8]

does your experimentally determined rate law concur with this expression?

GCT
Nov5-06, 03:44 PM
The rate law would be

rate=k(forward)[I-]^2[S2O8]

does your experimentally determined rate law concur with this expression?

loadsy
Nov5-06, 06:36 PM
Ahh I see what you are saying, yeah it's just
rate=k[S2O8^2-][I^-]^2

And my rate law does not coincide with this, therefore it cannot be a single-step mechanism. Gotcha! Thanks.