kittel nearly free electron model

[ehrenfest]

1. The problem statement, all variables and given/known data
This question refers to Kittel's solid-state physics book.

I just do not understand the 1D example on pages 164-65. So, I understand everything until the line "The wavefunctions at k = \pm \pi/a are not the traveling waves \exp(i\pi x/a) or \exp(i\pi x/a) of free electrons."

Kittel tries to explain, but I just don't understand. Is he saying that they will just bounce back and forth between k = pi/a and k = -pi/a by Bragg reflection? How does he know that!?!?!? PLEASE HELP!!


2. Relevant equations



3. The attempt at a solution

[genneth]

I'm afraid I don't understand what you don't understand. Isn't he just stating that electrons in a lattice aren't free?

[ehrenfest]

He is saying that it is only true for wavefunctions at k = \pm \pi/a.

genneth, do you have the book? If not then it will be hard to answer this question since I really don't understand like half a page after that and a figure on the previous page.

But thanks for your effort.

[ehrenfest]

anyone ?