Calculating \Delta_H for a Reaction: A Simple Guide

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SUMMARY

The discussion focuses on calculating the enthalpy change (\Delta_H) for the reaction CH_4 + 2O_2 \rightarrow CO_2 + 2H_2O. Participants confirm that the correct approach is to use the formula \sum _i \Delta_H_i - \sum _j \Delta_H_j, which involves subtracting the total enthalpy of the reactants from that of the products. It is emphasized that accurate values for the enthalpies of formation must be sourced from reliable reference materials, and attention must be paid to the signs and coefficients in the balanced equation.

PREREQUISITES
  • Understanding of chemical reactions and stoichiometry
  • Familiarity with enthalpy of formation concepts
  • Access to a reliable reference book or online database for enthalpy values
  • Basic knowledge of thermodynamics
NEXT STEPS
  • Research the enthalpy of formation values for common compounds like CH_4, O_2, CO_2, and H_2O
  • Learn about the significance of signs in thermodynamic equations
  • Explore advanced topics in thermodynamics, such as Hess's Law
  • Study the application of enthalpy calculations in real-world chemical processes
USEFUL FOR

Chemistry students, educators, and professionals involved in thermodynamics and reaction engineering will benefit from this discussion, particularly those focused on calculating reaction enthalpies.

courtrigrad
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Hello all

Let's say we are given:

[tex]CH_4 + 2O_2 \rightarrow CO_2 + 2H_2O[/tex]

We want to find [tex]\Delta_H[/tex] for the entire reaction.

Would I just use the formula:

[tex]\sum _i \Delta_H_i - \sum _j \Delta_H_j[/tex]? In other words just look up enthalpies in book and subtract enthalpy of reactants from enthalpy of products?

Thanks
 
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courtrigrad said:
Hello all

Let's say we are given:

[tex]CH_4 + 2O_2 \rightarrow CO_2 + 2H_2O[/tex]

We want to find [tex]\Delta_H[/tex] for the entire reaction.

Would I just use the formula:

[tex]\sum _i \Delta_H_i - \sum _j \Delta_H_j[/tex]? In other words just look up enthalpies in book and subtract enthalpy of reactants from enthalpy of products?

Thanks

IIRC,that's how it goes.To find the reaction enthalpy,u need to know the creation enthalpies for each of the components from the reaction.Pay attention with the signs.

Daniel.
 
for creating this guide, it's very helpful!

Hello! Yes, you are correct in using the formula \sum _i \Delta_H_i - \sum _j \Delta_H_j to calculate \Delta_H for this reaction. The \Delta_H values for each species can be found in a reference book or online database. Just make sure to use the correct units and to account for the coefficients in the balanced chemical equation. I'm glad the guide was helpful for you!
 

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