Why won't C4 explode when heated but a shockwave can set it off?

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C4 explosives do not detonate when heated because they undergo a slow combustion process rather than an explosive reaction. The primary reason for this behavior is the difference in reaction mechanisms; heat alone does not provide the necessary energy to break the chemical bonds in C4 for an explosive reaction. In contrast, a shockwave delivers a rapid mechanical force that can break these bonds, triggering the explosive reaction. This phenomenon is similar to the way egg whites do not transform into meringue through heat alone but require mechanical agitation to break bonds.

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I asked my chem teacher but they had no answer so maybe you guys know. Why is it that C4 won't explode when heated (why does it burn slowly?) but a shockwave will set it off?
 
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Serj said:
I asked my chem teacher but they had no answer so maybe you guys know. Why is it that C4 won't explode when heated (why does it burn slowly?) but a shockwave will set it off?

Simply put there are 2 different reaction mechanisms. This is not all that uncommon. In some polymer reactions

nA + Δ -> An while if severely stirred nA -> garbage.

The second example is a mechanical process of braking bonds. An common household example of this is egg whites. No matter how much heat you apply to an egg while you will never end up with a meringue. When you beat the egg whites you are actually braking bonds (yes you are also aerating it).
 

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