Can the Free Particle Wave Equation Be Solved for Periodic Boundary Conditions?

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SUMMARY

The discussion centers on solving the free particle wave equation under periodic boundary conditions, specifically within the interval from 0 to 2πL. The wave function is represented as a superposition of plane waves, expressed through Fourier transforms. The participants explore the implications of periodic eigen energy functions and the general solvability of the wave equation in this context. Patrick emphasizes that the wave equation describes the evolution of the wave function over time, which varies based on the physical situation, such as whether the particle is free or subject to a potential.

PREREQUISITES
  • Understanding of Fourier transforms and their applications in quantum mechanics
  • Familiarity with wave functions and their role in describing quantum states
  • Knowledge of boundary conditions in differential equations
  • Basic principles of quantum mechanics, particularly regarding free particles
NEXT STEPS
  • Research periodic boundary conditions in quantum mechanics
  • Study the implications of the Schrödinger equation for free particles
  • Explore the concept of eigenfunctions and eigenvalues in quantum systems
  • Learn about the role of delta functions in wave function representation
USEFUL FOR

Quantum physicists, students of quantum mechanics, and researchers interested in wave function behavior under periodic conditions will benefit from this discussion.

sniffer
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for a free particle, the wave equation is a superposition of plane waves,

[tex]\psi(x,0)= \int_{-\infty}^{\infty}g(k)\exp(ikx)dk[/tex]
and
[tex]g(k)= \int_{-\infty}^{\infty}\psi(0,0)\exp(-ikx)dx[/tex]

one is the Fourier transform of the other. some cases to solve this is when we assume a small delta k, so g(k) behaves like a pulse "delta" function.

is there any more general case we can solve this?

i have been thinking hard if we have definite periodic x, say from 0 up to [itex]2\pi L[/itex], is it solvable?

what would be the (periodic) eigen energy function (if it is)?
 
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sniffer said:
for a free particle, the wave equation is a superposition of plane waves,

[tex]\psi(x,0)= \int_{-\infty}^{\infty}g(k)\exp(ikx)dk[/tex]
and
[tex]g(k)= \int_{-\infty}^{\infty}\psi(0,0)\exp(-ikx)dx[/tex]

one is the Fourier transform of the other. some cases to solve this is when we assume a small delta k, so g(k) behaves like a pulse "delta" function.

The above pair is, as you say, a Fourier transform pair. Any "nice" function can be written that way, so the above is not a "wave equation" or something, it is a general way of writing a function.
The quantum state of a single scalar particle is described by just such a nice function, called the wave function. At any time, it can be (almost) any function. However, what the wave equation (not written here) gives you, is how this wavefunction AT A CERTAIN TIME t0 will change into the wavefunction at another time t1. This equation will be different according to the situation at hand (free particle, particle in a potential...).

cheers,
Patrick.
 

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