Question about electric potential energy - need confirmation

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SUMMARY

The discussion focuses on calculating the potential energy per ion in an infinite one-dimensional ionic crystal composed of alternating charges of magnitude e. The potential energy is derived using the formula u_n = (e^2 / (4 π ε_0 d)) * Σ[(-1)^(i-1) * (1 - n/i)] as n approaches infinity, leading to the conclusion that the potential energy per ion equals -(e^2 / (4 π ε_0 d)) * ln(2). The final steps confirm that the series diverges, but dividing by n results in zero, validating the calculation of potential energy per ion.

PREREQUISITES
  • Understanding of electrostatics and potential energy concepts
  • Familiarity with series expansions, particularly the power series for ln(1+x)
  • Knowledge of ionic crystals and their charge interactions
  • Basic calculus, specifically limits and summation techniques
NEXT STEPS
  • Study the derivation of potential energy in ionic crystals using electrostatic principles
  • Explore the properties of alternating series and their convergence behavior
  • Learn about the implications of potential energy calculations in solid-state physics
  • Investigate the applications of ln(2) in physical chemistry and materials science
USEFUL FOR

Students and professionals in physics, particularly those focusing on electromagnetism, solid-state physics, and materials science, will benefit from this discussion.

Kelvin
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This is a homework problem of a EM course:

Calculate the potential energy, per ion, for an infinite one-dimensional ionic crystal, that is, a row of equally spaced charges of magnitude e and alternating sign.
Hint: The power series expansion of ln(1+x) may be useful.


Here's my calculation:

Let [tex]u_n[/tex] be the potential energy when there is n charges.
[tex]u_1 = 0[/tex]

[tex]u_2 = \frac{1}{4 \pi \epsilon_0} \frac{-e^2}{d}[/tex] where d is the separation of two charges

[tex]u_3 = \frac{1}{4 \pi \epsilon_0} \left( 2\times \frac{-e^2}{d} + \frac{e^2}{2d}\right)[/tex]

[tex]u_4 = \frac{1}{4 \pi \epsilon_0} \left( 3 \times \frac{-e^2}{d} + 2 \times \frac{e^2}{2d} + \frac{-e^2}{3d}\right)[/tex]

...

[tex]u_n = \frac{1}{4 \pi \epsilon_0} \left( (n-1) \times \frac{-e^2}{d} + (n-2) \times \frac{e^2}{2d} + \dots + \frac{(-1)^{n-1} e^2}{(n-1)d}\right)[/tex]

[tex]= \frac{e^2}{4 \pi \epsilon_0 d} \sum_{i=1}^{n-1} \frac{(-1)^i (n-i)}{i}[/tex]

[tex]= \frac{e^2}{4 \pi \epsilon_0 d} \sum_{i=1}^{n-1} (-1)^{i-1} \left( 1- \frac{n}{i} \right)[/tex]

[tex]= \frac{e^2}{4 \pi \epsilon_0 d} \left( \sum_{i=1}^{n-1} (-1)^{i-1} - n \sum_{i=1}^{n-1}\frac{(-1)^{i-1}}{i} \right)[/tex]

potential energy per ion
= [tex]u_n/n = \frac{e^2}{4 \pi \epsilon_0 d} \left( \frac{1}{n}\sum_{i=1}^{n-1} (-1)^{i-1} - \sum_{i=1}^{n-1}\frac{(-1)^{i-1}}{i} \right)[/tex]

as n tends to infinity,

[tex]u_n/n = \frac{e^2}{4 \pi \epsilon_0 d}\left( 0 - \ln 2 \right)[/tex]

I am not sure my last 2 steps are correct or not. The series [tex]\sum_{i=1}^{n-1}(-1)^{i-1}[/tex] diverges as n tends to infinity. If we divide the series by n, do we get really zero?

Thanks for your help!
 
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While you probably don't need this since it was 6 years ago: I just completed this problem on a practice GRE test and the solution is easier if you read the question closely. It asks for the potential energy per ion, as opposed to the entire system. This allows the summation to fall out with a ln(2) included. Hope this helps to future readers!
 

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