Ground Level Ozone Production: Reaction Mechanism

[adeel]

Hi, I need help with the following question:

What are mechanisms of reactions that lead to the production of ground level ozone

the chemical reaction is

sunlight + VOCs + NOx -> Smog and Ozone

can someone tell me what the mechanism is or how to develope the mechanism

 

[GCT]

It might be listed under the environmental chemistry section in a standard principles of chemistry book (e.g. chemistry by raymond chang).

 

[Monique]

It's a chain reaction set off by free radicals.. I'd have to look up the details, that is all that I remember :)

 

[Monique]

Here is a little more info, it confirms my suspicion:

"In the upper atmosphere free radicals are produced through dissociation of the source molecules, particularly the normally unreactive chlorofluorocarbons by solar ultraviolet radiation or by reactions with other stratospheric constituents. These free radicals then react with ozone in a catalytic chain reaction which destroys the ozone, but regenerates the free radical, allowing it to participate in additional reactions. Such reactions are believed to be the primary cause of depletion of the ozone layer and are the reason why the use of chlorofluorocarbons as refridgerants has been restricted."