What is the Color of Green Copper?

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Discussion Overview

The discussion centers on the color of oxidized copper, specifically addressing why the Statue of Liberty appears green. Participants explore various chemical compounds and oxidation states of copper that may contribute to this coloration, including references to other forms of oxidized copper such as those found in old pennies.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification, Debate/contested

Main Points Raised

  • Some participants note that pure copper is orange or pink when anodized, while oxidized forms like copper hydroxide are blue and copper oxide is black.
  • Others suggest that the green color results from oxidation processes, with one participant mentioning that they have observed copper turning green.
  • Several participants reference the green color of old pennies as a similar phenomenon.
  • One participant proposes that there are multiple oxidation states of copper, with at least one being green.
  • Another participant speculates that the green color of the Statue of Liberty could be due to copper carbonate, mentioning the role of carbonic acid formed from rain reacting with copper.
  • It is mentioned that sulfates and acetates can also cause copper to turn green.
  • A link to a Wikipedia page on copper carbonate is provided for further reference.

Areas of Agreement / Disagreement

Participants express various hypotheses regarding the chemical processes involved in the green coloration of copper, but no consensus is reached on a single explanation or the specific compounds responsible.

Contextual Notes

Some claims depend on assumptions about chemical reactions and the specific environmental conditions affecting copper oxidation, which are not fully detailed in the discussion.

ShawnD
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Pure copper metal is orange (or pink after being anodized), copper hydroxide is blue, copper oxide is black. So then why is the statue of liberty green?
 
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Supposedly its oxidation... and I've seen copper turn green though too..
 
I've seen lots of old pennies turn green. Must be the same thing.
 
I'm no chemist, but I believe there are several different oxidation states of copper, one of which is green.

- Warren
 
ShawnD said:
Pure copper metal is orange (or pink after being anodized), copper hydroxide is blue, copper oxide is black. So then why is the statue of liberty green?

My guess was copper sulfate, but I looked it up and its probably more likely copper carbonate. As you may have learned in your intro chem classes(especially if your teacher was an environmental guy like mine) water reacts with carbon dioxide to form carbonic acid, which gives all rain its slight acidity. This carbonic acid will then react with the copper to form cupirc and cuprous carbonate.
 
sulfates and acetates will turn it green.
 

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