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Amok
#1
Jan28-12, 08:36 AM
P: 255
Hi,

Can anyone help derive the rate law for the Eigen wilkins reaction mechanism? The derivation in the wikipedia entry (http://en.wikipedia.org/wiki/Eigen-Wilkins_Mechanism) is confusing, but the rate law is correct. I can't figure out if they make a "steady-state" approximation or a pre-equilibrium approximation, but I'm pretty sure it's both (weird).
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