@TCups
I have read every post in this thread and have seen no reply to your "Primary Containment explosion" theory which addresses the following:
There is no question in my mind that Hydrogen escaping from the SFP's (or by some path out of the reactor core) could (and did) explode once it mixed with relatively dry air above the SPFs. However, I believe there would be insufficient Oxygen available within the Primary Containment for a Hydrogen explosion to occur there for the following reasons.
Consider the reaction which produces the Hydrogen;
Zr + 2 H2O = ZrO2 + 2 H2
In this reaction, all of the Oxygen in a water molecule is "fixed" on the surface of the fuel cladding in the form of zirconium oxide.
When Hydrogen burns (explodes), there is one molecule of Oxygen for each molecule of Hydrogen;
2 H2 + O2 ---> 2 H2O
The only other source for Oxygen within the RPV / Primary Containment might be the release of air entrained or dissolved in the cooling seawater or Oxygen released directly from the core via radiolysis of the surrounding water/steam.
The radiolysis source is questionable since it occurs at twice the temp of a redox reaction (between water and zirconium) and the heat source in the core is decay heat not fission generated.
The seawater source is more problematic...
Flamable/explosive gases such as Hydrogen have something called UEL or Upper Explosive Limit.
See;
[
http://en.wikipedia.org/wiki/Flammability_limit]
"Upper Explosive Limit (UEL): Highest concentration (percentage) of a gas or a vapor in air capable of producing a flash of fire in presence of an ignition source (arc, flame, heat). Concentrations higher than UEL are "too rich" to burn."
From the table at the same link, Hydrogen's UEL in % by volume of air is 75%. Air is composed of about 21% by volume Oxygen. I expect that these figures are at STP for dry air and would need to be adjusted for the temperature and pressure in the Primary Containment. Additionally, the presence of steam in the same space as the Hydrogen and Oxygen inhibits their reaction. Thus, when the Hydrogen mixes with relatively dry air above the SPFs it can explode... but perhaps not while it is within the steamy Primary Containment.
Maybe one of our Nuclear Engineers can address your theory from this perspective.
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