Why Does Maxwell's Speed Distribution Law Use Exponential Functions?

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Homework Help Overview

The discussion revolves around the derivation of Maxwell's speed distribution law for gases, specifically addressing the use of exponential functions in the context of independent velocity components.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants explore the relationship between the joint probability of independent velocity components and the properties of exponential functions. Questions arise regarding the interpretation of the combined probability and the role of the partition function.

Discussion Status

The discussion is active, with participants questioning the assumptions behind the derivation and exploring the implications of independence among velocity components. Some guidance is offered regarding the mathematical relationships involved, but no consensus has been reached.

Contextual Notes

There is uncertainty regarding the definition and role of the partition function in this context, as well as the interpretation of the joint probability in relation to the individual components.

Kolahal Bhattacharya
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In a non-traditional type of derivation of Maxwell's speed distribution for gases,I happen to face the following problem:
They say since P(v_x),P(v_y),P(v_z) are independent,so the combined probability wil be P=P(v_x)P(v_y)P(v_z).
This much is OK.Then they say the only function having the property f(a+b+c)=f(a)f(b)f(c)
is an exponential function.So, consider the P(v_x) as to have exponential dependence P(v_x)=K exp[-L*(v_x)^2].This makes me uncomfortable.Did we have P=P(v_x+P_y+P_z)?I am a bit new to statistical ideas,so really cannot be sure when we said the joint probability is P,it means P=P(v_x+P_y+P_z).
Please help.
 
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Do you what a partition function is?
 
OK, I do not know.Is P acting as a partition function here?How do we know that?And after all,what does it do?
 
I think the argument holds because

[tex]V^2 = V_x^2 + V_y^2 + V_z^2[/tex]
therefore
[tex]P(V^2) = P( V_x^2 + V_y^2 + V_z^2 )[/tex]
and the next step follows from the independence of V_x, V_y and V_z.
 
Thank you all very much
 

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