Understanding a proof of Carnot's theorem.

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Discussion Overview

The discussion revolves around understanding a proof of Carnot's theorem, particularly focusing on the implications of the theorem regarding the efficiency of hypothetical engines compared to Carnot engines. Participants explore the reasoning behind the proof and its consequences for the second law of thermodynamics.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions the proof's implication that either the second law is incorrect or that the Carnot engine is not the most efficient, suggesting a hypothetical less efficient engine could also be used to construct a similar argument.
  • Another participant asserts that any process with efficiency less than Carnot efficiency is not reversible, implying a limitation in the reasoning presented.
  • A later reply acknowledges the previous point, indicating a realization of the oversight.
  • One participant raises a question about the efficiency definition in the context of the Carnot engine functioning as a refrigerator, suggesting a potential misunderstanding of efficiency versus coefficient of performance.
  • Another participant clarifies that the discussion is about efficiency, not coefficient of performance, and emphasizes the need to convert between the two when necessary.

Areas of Agreement / Disagreement

Participants express differing views on the implications of the proof and the definitions of efficiency versus coefficient of performance. The discussion remains unresolved regarding the initial participant's concerns about the proof's validity.

Contextual Notes

There are unresolved assumptions regarding the definitions of efficiency and coefficient of performance, as well as the implications of reversibility in thermodynamic processes.

Fallen Seraph
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[SOLVED] Understanding a proof of Carnot's theorem.

I'm having trouble understand this proof of Carnot's theorem, and I would appreciate it if someone could point out where my reasoning goes wrong.

The proof reads thusly:


Suppose there exists a a hypothetical engine with a greater efficiency than a Carnot engine.

Consider this engine working from the same hot and cold reservoirs as a Carnot engine.

Adjust the cycle of the Carnot engine such that its work output == that of the hypothetical engine == W

Since the Carnot engine is reversable, we can turn it into a refrigerator that takes in work W from the hypothetical engine and energy Q2 from the cold reservoir and then outputs energy Q1 into the hot reservoir.

Let the energy taken from the hot reservoir by the hypothetical engine == P1.

We have that the efficiency of the hypothetical engine is greater than that of the Carnot one, so

W/P1>W/Q1

=>

Q1>P1.

This means that our construction is taking heat from the cold reservoir, and depositing it in the hot one. Which violates the 2nd law, and thus proves the theorem.


My problem with it is that is seems to imply that either the second law is wrong, or the Carnot engine is not the most efficient because:

Why not just get an engine that is less efficient than the Carnot one and construct the same device as was made in the proof except with the Carnot engine in the place that the hypothetical one occupied in the proof, and the less efficient engine in the place of the Carnot?

This, as far as I can see, would also move heat from the cold reservoir to the hot one.

What am I missing?

Thanks in advance.
 
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Fallen Seraph said:
What am I missing?

Any process with efficiency less than Carnot efficiency is not reversible, for example.
 
Ah! So it is!

Thank you.
 


This Carnot engine works as refrigerator. So, shouldn't it eficiency be Q2/W and not W/Q1?
 
that's not efficiency,that's co-efficient of performance..
we are working with efficiency here so if we take coefficient of performance we must have to convert it into efficiency through the relation between them finally..:)
 

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