|Apr17-08, 11:12 PM||#1|
Does anybody know why thorium is better than uranium as far as heat transfer is concerned?
|Apr18-08, 04:44 PM||#2|
Th has slightly lower atomic mass than U do it would offer less resistance to phonon conduction.
Th-Th bond length = 359.5 pm
U-U bond length = 277 pm
Space group: Fm-3m (Space group number: 225)
Structure: ccp (cubic close-packed)
a: 508.42 pm
b: 508.42 pm
c: 508.42 pm
Space group: Cmcm (Space group number: 63)
a: 285.37 pm
b: 586.95 pm
c: 495.48 pm
I suspect that the orthorhombic crystal with different lengths in all three dimensions plays the biggest role in the lower thermal conductivity of U as compare to Th, which has a closed packed cubic structure.
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