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Solvent and UV/V spec

 
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Sep6-08, 02:53 AM   #1
 
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Solvent and UV/V spec


Ah this is a question because I'm new to UV/V spec.
What would a solvent do to a spectra of a compound when it is analyzed?

Such as a polar/non nonpolar solvent on benzophenone?

solvents such as:
Nonpolar :Ethanol, Cyclohexane, n-Hexane
Polar: Methylene chloride

I looked online but couldn't find a simple description of things that would occur.

I do think that the solvents could produce additional peaks on the spectra due to it absorbing/reflecting at certain wavelengths but other than that I'm not sure.

Thanks alot
 
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Sep7-08, 08:29 PM   #2
GCT
 
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I remember something along the lines of solvent broadening - increasing the bandwidth of the peaks - , along with something with do with shifts , or perhaps reflection ... Instrumental Analysis by Skoog should help , I'm going read upon this topic and answer your question when I have time.
 
Sep7-08, 09:53 PM   #3
 
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Quote by GCT View Post
I remember something along the lines of solvent broadening - increasing the bandwidth of the peaks - , along with something with do with shifts , or perhaps reflection ... Instrumental Analysis by Skoog should help , I'm going read upon this topic and answer your question when I have time.
Ah okay then.
Thank you GCT
 
Sep8-08, 10:28 AM   #4

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Solvent and UV/V spec


Search terms: "Bathochromic Shift" and Hypsochromic Shift"
 
Sep12-08, 06:35 PM   #5
 
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Thank you both.
 
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