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Derive the expression for isothermal change in Constant Volume Heat Capacity

 
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Sep22-09, 10:14 PM   #1
 

Derive the expression for isothermal change in Constant Volume Heat Capacity


1. The problem statement, all variables and given/known data
Derive the following expression for calculating the isothermal change in Constant Volume Heat Capacity:

(dCv/dV)T = T(d2P/dT2)V


2. Relevant equations



3. The attempt at a solution

I have no idea, please help
1. The problem statement, all variables and given/known data



2. Relevant equations



3. The attempt at a solution
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Sep22-09, 10:37 PM   #2
 
How about this?????

assuming ideal gas:

P=nrt/V

then

(dP/dT) = R/V , ignoring moles

and

(d2P/d2T) = 0

so (dCv/dV)=T*0=0
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