Calculating Heat of Reaction: AgNO3 + HCL = AgCl + HNO3 | kcal/mole Formula

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Discussion Overview

The discussion revolves around calculating the heat of reaction for the reaction between silver nitrate (AgNO3) and hydrochloric acid (HCl) to produce silver chloride (AgCl) and nitric acid (HNO3). Participants explore how to determine the heat of reaction in terms of kcal per mole of AgNO3, discussing various approaches and calculations related to this problem.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant asks how to calculate the heat of reaction in kcal/mole of AgNO3, indicating a need for a formula.
  • Another participant suggests using a proportion based on the given heat and mass of AgNO3 to find the heat per mole, providing molar masses for calculation.
  • A different participant presents a calculation that results in 56555.8 kcal/mole of AgNO3, questioning its correctness.
  • One participant affirms the correctness of the calculation through unit analysis.
  • Another participant introduces the concept of heat of formation, suggesting a different approach to find the heat of formation of AgNO3 using thermodynamic data.

Areas of Agreement / Disagreement

There is no consensus on the correct method to calculate the heat of reaction, as participants propose different approaches and interpretations of the problem. Some focus on direct calculations, while others suggest using heat of formation data.

Contextual Notes

Participants reference specific molar masses and thermodynamic concepts, but there is no resolution on the assumptions or definitions required for the calculations. The discussion includes various interpretations of the problem's requirements.

Who May Find This Useful

Students studying thermodynamics, chemistry, or related fields may find this discussion useful for understanding different methods of calculating heat of reactions and the application of thermodynamic data.

dg_5021
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In the reaction shown below, 699 kcal of heat are liberated when 2.10 g of AgNO3 reacts with HCL:
AgNO3(aq) + HCL(aq) = AgCl(s) + HNO3(aq)
What is the heat of reaction in terms of kcal/mole of AgNO3?

How do u do this problem? Is there a formula for it?
 
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I am surprised how you didn't see this, but it's no problem since you try to learn something and asked this question.

Okay, 2.10 grams of AgNO3 give 699 kcal of thermal energy (heat), right? Then solve a simple proportion, like "2.10 grams give 699 kcal, then one mole of AgNO3 gives that". Remember that you can use 107.8, 14.0, and 16.0 g/mol for silver, nitrogen, and oxygen respectively, to find how many grams of AgNO3 are there in one mole of compound.

If there is another point you haven't understood yet, don't hesitate to ask.

Take care.
 
what i did was divide (699kcal /2.10g AgNo3) x (169.91 g AgNo3/ 1mol AgNo3) = 56555.8 kcal/mole of AgNo3

is this correct?
 
It seems to be correct. Unit analysis gives the same result.
 
thanks for the help
 
Do you mean what is the Heat of formation of AgNO3?
If this is the question then, turn 2.1 g of AgNO3 into moles. THen for the reaction, the the heat of the reaction is= sum(moles x H of formation of products)-sum(moles x H of formation of reactants). You should have a table of thermodynamic data in the back of you text with the heats of formation for everything except maybe AgNO3 which is what you are trying to find. You are given the heat of the reaction so just solve the equation for the heat of formation of AgNO3.
 

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