| New Reply |
Relationship between photochemical mechanisms and chiral molecules |
Share Thread | Thread Tools |
| Mar15-13, 04:55 PM | #1 |
|
|
Relationship between photochemical mechanisms and chiral molecules
I'm way outside my realm of knowledge here so perhaps I need some help polishing my question or the concepts behind it. Thank you for your patience.
Does the orientation of circularly polarized light (CPL) as a reaction mechanism influence the chirality of the molecule in a general manner, such as left handed circularly polarized light creates levorotatory molecules? More importantly, does CPL influence the optical activity in a similarly consistent manner? L/D chiral conventions are based on nomenclature rules and therefore I suspect any influence would be coincidental. How would I Google or go about collecting data for my question? |
| Mar15-13, 06:30 PM | #2 |
|
|
I do know that starting in the 1970s if not earlier many observations have been made of chirally asymetric photochemical reactions promoted by circularly polarised light, though as far as I know the effects have always been quite small.
More often than not the work is done with origin of life very much in mind. |
| Mar22-13, 09:26 PM | #3 |
|
|
Thanks for the response. The relationship light has with life has been on my mind recently.
|
| New Reply |
| Thread Tools | |
Similar Threads for: Relationship between photochemical mechanisms and chiral molecules
|
||||
| Thread | Forum | Replies | ||
| Why and how chiral molecules rotate plane of polarisation? | Chemistry | 4 | ||
| Why is it only chiral molecules that rotate plane polarized light? | Chemistry | 2 | ||
| Specific Rotation of Chiral Molecules | Biology, Chemistry & Other Homework | 3 | ||
| chiral centres in molecules | Biology, Chemistry & Other Homework | 0 | ||
| relationship for molecules | General Physics | 1 | ||