Getting Aluminium Chloride from Aluminium & Hydrochloric Acid

  • Thread starter Thread starter c_d
  • Start date Start date
  • Tags Tags
    Aluminium
Click For Summary

Discussion Overview

The discussion revolves around the chemical reaction between aluminium and hydrochloric acid to produce aluminium chloride. Participants explore the feasibility of isolating pure aluminium chloride from the resulting solution, considering various methods and the implications of hydrolysis.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant describes the reaction producing aluminium chloride dissolved in water and questions whether boiling the water would yield pure aluminium chloride as a white powder.
  • Another participant challenges this idea, stating that aluminium chloride will hydrolyse rapidly to form aluminium hydroxide, suggesting that the initial assumption may not hold.
  • A different participant proposes that aluminium trichloride could be soluble in dichloromethane and suggests checking reliable sources for confirmation.
  • Another participant argues that once water is associated with Al3+, it becomes difficult to remove it, suggesting that mixing the hydrated chloride with ammonium chloride and heating might be a potential method for extraction.
  • This participant also recommends starting with aluminium metal and treating it with dry hydrochloric acid or dry chlorine gas to avoid hydrolysis complications.

Areas of Agreement / Disagreement

Participants express differing views on the feasibility of isolating pure aluminium chloride from the reaction, with some asserting that hydrolysis complicates the process, while others propose alternative extraction methods. No consensus is reached on the best approach.

Contextual Notes

The discussion highlights the complexity of the hydrolysis of aluminium chloride and the challenges associated with its extraction, indicating a dependence on specific conditions and methods that remain unresolved.

c_d
Messages
6
Reaction score
0
Hi,

If I mix aluminium (tin foil) with hydrochloric acid I get the following reaction:

2Al(s) + 6HCl(aq) -> 2AlCl3(aq) + 3H2(g)

So I end up with aluminium chloride disolved in the water.

If I boiled the water would I be left with pure aluminium chloride? I'm thinking the water will boil away leaving the AlCl3, which should be a white powder.
 
Chemistry news on Phys.org
c_d said:
Hi,

If I mix aluminium (tin foil) with hydrochloric acid I get the following reaction:

2Al(s) + 6HCl(aq) -> 2AlCl3(aq) + 3H2(g)

So I end up with aluminium chloride disolved in the water.
Not really. AlCl3 will hydrolyse rapidly forming Al(OH)3.
 
i believe that aluminum trichloride is soluble in dichloromethane, and could be extracted. (not 100% sure about this though - you may want to double check the Merck index of other suitable source).
 
Nah, once you get the H2O clustered around the Al3+, it's tough to get it out of there. As with the FeCl3 thread, I think you might be able to do so by mixing the hydrated chloride with ammonium chloride, and then heating that.

The bst way is to start with Al metal and treat it with dry HCl (gas) or dry Cl2. Once you let hydroxies in, they're going to want to stay - extraction isn't going to work.
 

Similar threads

  • · Replies 1 ·
Replies
1
Views
4K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 7 ·
Replies
7
Views
4K
  • · Replies 6 ·
Replies
6
Views
5K
  • · Replies 11 ·
Replies
11
Views
6K
  • · Replies 8 ·
Replies
8
Views
4K
Replies
1
Views
3K
  • · Replies 2 ·
Replies
2
Views
3K
Replies
43
Views
24K
Replies
12
Views
6K