What is the Constant Volume Specific Heat for Diatomic Gases?

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Homework Help Overview

The discussion revolves around the specific heat constants for diatomic gases, particularly focusing on the constant volume specific heat (C_v) and its relationship to constant pressure specific heat (C_p). Participants are exploring definitions and properties related to these thermodynamic concepts.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants are attempting to locate specific heat constants and clarify the definitions of C_v and C_p. There are discussions about the relationship between these constants and the degrees of freedom for different types of gases.

Discussion Status

Some participants have provided guidance on where to find specific heat values and have discussed the relationships between C_p and C_v. There are differing views on the degrees of freedom for diatomic gases, indicating an exploration of multiple interpretations.

Contextual Notes

There is mention of temperature dependence affecting the degrees of freedom for diatomic gases, particularly at high temperatures, which may influence the values of specific heat constants being discussed.

melanie
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Just trying to locate specific heat constants with constant volume (not pressure), any ideas where to find this?
 
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If you have a thermodynamic set of property tables it would be in the column with Cv (v should be a subscript) if you are looking at Cp that is the specific heat at constant pressure. They should be fairly close in most non-extreme conditions so becareful what your looking at
 
[itex]C_p[/itex] : Specific Heat at constant pressure
[itex]C_v[/itex] : Specific Heat at constant volume

Also [itex]C_p - C_v = R[/itex]

[itex]\frac {C_p}{C_v} = lamda[/itex]

where lamda = [itex]1 + \frac {2}{f}[/itex]

Where f=degrees of freedon

for monoatomic gas , f=3
for diatomic gas , f=3

You can solve for two expressions at the top to get Cp

BJ
 
One correction to Dr.Brain's post. f for diatomic gases is 5
 
quark said:
One correction to Dr.Brain's post. f for diatomic gases is 5
And that's only at around room temperature's where the vibrational degree of freedom is absent. At high temperatures, f will be 7 for diatomic gases.
 

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