Why Wave Function Extends in Finite Potential Well

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SUMMARY

The discussion focuses on the behavior of wave functions in a finite potential well as the energy of a bound state increases. The wave function inside the well is represented as Asin(lx) + Bcos(lx), while outside the well it is expressed as Fe^(-ka), where k is defined as Sqrt[-2mE]/hbar. As energy increases, the exponent becomes less negative, resulting in a wave function that extends further outside the well, thereby increasing the probability of finding the particle outside the barrier. This phenomenon is corroborated by the transmission coefficient calculations, illustrating that higher energy states correspond to greater tunneling probabilities.

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  • Understanding of quantum mechanics principles, particularly wave functions
  • Familiarity with finite potential wells and bound states
  • Knowledge of mathematical functions, specifically exponential decay
  • Basic grasp of tunneling phenomena in quantum physics
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  • Study the mathematical derivation of wave functions in quantum mechanics
  • Explore the concept of tunneling coefficients in quantum mechanics
  • Learn about the implications of energy levels in finite potential wells
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Students and professionals in physics, particularly those specializing in quantum mechanics, as well as educators seeking to explain wave function behavior in finite potential wells.

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I need to explain why, as the energy of a bound state in a finite potential well increases, the wave function extends more outside of the well. I need to do this from both a mathematical and a physical point of view. I think I know the mathematical explanation (see attached image). Can anyone help me with the physical explanation?
 

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I don't think you quite understand the physics or the math of the problem yet.

To answer your question quickly, the wave function inside the well is:
Asin(lx) + Bcos(lx)

outside the well is:
Fe^(-ka) where k: Sqrt[-2mE]/hbar (k is real because E<0)

Now when you INCREASE the energy, you are actually making the exponent "less negative." For example, if you original E made the wave function Fe^(-5) and then you increased the energy, your new wave function would look like Fe^(-1). Now you can easily check on your calculator that e^(-5) decays faster than e^(-1), hence the bigger energy will have a larger wave function outside the barrier, making it more probable.

You can also check this by explicitly calculating the transmission coefficient, which will yield the correct answer again (at least it did on this little napkin here).

Physically, things with higher energies have higher tunnelling coefficients. Imagine you are diving into a deep pool of sand (or punching thru a wall). The faster your body is moving right before you hit the sand (or the faster your fist is going right before you hit the wall) the more energy you will have and the deeper you will go into the sand (or the better your chances are to break a hole in the wall).
 

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