Recent content by JulesP
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Gibbs energy for Lithiation in Lithium batteries
So to be clear, the three figures for charge capacity are: theoretical specific charge capacity (Ah/kg from the molar masses), theoretical charge capacity for a specific battery (Ah and based on the masses of its active ingredients), and lastly the working charge capacity derived from actual... -
Gibbs energy for Lithiation in Lithium batteries
I have revised the calculations and page based on your feedback and this is here: Revised Calculations I was using an approach that had previously worked but translated it across incorrectly. Thanks -
Gibbs energy for Lithiation in Lithium batteries
On second thoughts, I don't wish to bore anyone with all the details of my proposals for showing if IPC-related energy gains are from internal enthalpy or the local environment, as part of an open system, so I will just show the calculation for the charge and energy capacity of a specific... -
Gibbs energy for Lithiation in Lithium batteries
Thank you. If I may, I will assemble my thoughts in a 1-2 page document over the next week, laying out the workable calculations. I would like to post that here, as a pdf or a link to it, and would appreciate your comments and thoughts on it. This is for preparations for a second research study... -
Gibbs energy for Lithiation in Lithium batteries
Thanks. I have requested the full article via ResearchGate. As I understand it, the overall reaction is: LiFePO4 + 6xC ⇄ Li(1-x)FePO4 + Li(x)C6 (I haven’t used the proper subscript formatting here) but the proportion ‘x’ makes the calculations difficult. Just looking at charging, the only... -
Gibbs energy for Lithiation in Lithium batteries
Thank you. I have only just found your reply! I got no email notice and I have posted something similar again today. When you write Li1 you mean monoatomic and non-ionic Lithium and with Li non-attached Lithium + ions? -
Reaction energy for a Lithium Iron Phosphate battery
For my battery research, I am trying to determine the reaction (Gibbs) energy for what occurs in a LiFePO4 battery as it discharges. For reference, I have used the approach that works for a Pb-Acid battery, as laid out below using molar masses, and am then trying to do the same for the LiFePO4... -
Gibbs energy for Lithiation in Lithium batteries
In writing up a paper on some research work on the effects of transients on Lithium Iron Phosphate batteries, I am laying out the thermodynamics and energetics for the reaction laid out below, but am having trouble finding the numbers for the reaction. Does anyone know the correct figures to... -
Lead Acid Battery Flyback Pulses: Electrolyte Decomposition
It was a personal comment from a fellow researcher. So I am not in a position to reference it. . . . -
Lead Acid Battery Flyback Pulses: Electrolyte Decomposition
Only in part. While pulses can apparently be used to break up Sulphate deposits, I have also heard that the voltage of pulses, once they meet the battery, is effectively grounded due to the low impedance of the pulse-producing coil and the battery itself. As such they are no longer in a position... -
Lead Acid Battery Flyback Pulses: Electrolyte Decomposition
Can inductively generated flyback pulses (~1kV) cause the decomposition or ‘consumption’ of any components in the electrolyte of a lead acid battery resulting in an energy release?