hi
you may find the answer at "http://answers.yahoo.com/question/index;_ylt=AuunKfjGksf89bitoh96qNT_xQt.;_ylv=3?qid=20071007013353AAIQvZZ"
the voltage of electrochemical cell ,as you know from nernst equation is concentration dependent and when it used for a long time it will consumed and the...