Estimate pH of KMnO4: Is It Neutral?

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Discussion Overview

The discussion revolves around estimating the pH of a potassium permanganate (KMnO4) solution, exploring whether it can be considered neutral. The scope includes theoretical considerations of acid-base properties and redox reactions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant suggests that KMnO4 is neutral, questioning if this neutrality is due to its involvement in redox reactions rather than acid/base interactions.
  • Another participant notes that KMnO4 is a salt derived from a strong base and a strong acid, implying it may be neutral.
  • A participant inquires about the Ka value for permanganic acid, indicating uncertainty about its classification as strong or weak.
  • A later reply provides a pKa value of -0.3 for permanganic acid at ionic strength 1.0, which may suggest a strong acid behavior.
  • One participant describes KMnO4 as a highly oxidized salt, which they argue does not affect its pH.

Areas of Agreement / Disagreement

Participants express differing views on the pH of KMnO4, with some asserting it is neutral while others raise questions about the acid-base properties of permanganic acid. The discussion remains unresolved regarding the definitive pH classification.

Contextual Notes

There are limitations regarding the availability of reference materials and the specific classification of permanganic acid, which may affect the conclusions drawn about the pH of KMnO4.

Mantas
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How could I estimate the pH of KMnO4 solution (strong oxidizer)? I believe it is neutral, but is that because it takes part in redox reactions and not acid/base or another reason?
 
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Hint: it is a salt of a strong base and strong acid (HMnO4).
 
Do you have the Ka value for Permanganic Acid? I'm about 500 miles removed from my CRC. Permanganic acid and the MnO4- salts are not on any of my reference materials as being a strong/weak anything. I do know that MnO4- is a great oxidizer though.
 
pKa = -0.3 (for ionic strength 1.0).
 
it's a highly oxidized salt
 

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