Alphabetical Order for Alkanes with Halogens and Alkyl Groups

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SUMMARY

The discussion focuses on the nomenclature of alkanes containing both alkyl groups and halogens. The primary rule is to assign the lowest possible numbers to substituents, regardless of whether they are alkyl groups or halogens. In cases where substituents can receive the same lowest number, the alphabetical order dictates that halogens, such as "chloro," take precedence over alkyl groups. This ensures that the naming follows IUPAC conventions accurately.

PREREQUISITES
  • Understanding of IUPAC nomenclature for organic compounds
  • Familiarity with alkyl groups and halogens
  • Knowledge of the lowest sum rule in chemical naming
  • Basic principles of chemical structure representation
NEXT STEPS
  • Study IUPAC nomenclature rules for complex organic compounds
  • Learn about the priority of functional groups in chemical naming
  • Explore examples of naming alkanes with multiple substituents
  • Review the concept of stereochemistry in organic compounds
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Chemistry students, educators, and anyone involved in organic chemistry who seeks to understand the rules of naming alkanes with substituents effectively.

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Homework Statement


For chemistry I have to name alkanes, however there is this one that I am unsure of. This one consists of both alkyl groups and halogens. Would I make my alkyl group the lowest possible number or my halogen group, or does it not matter as long as I use the lowest possible number? And does the alphabetical rule apply if I have a halogen and an alkyl group or would I put my alkyl group first because of the 'priority order'?

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The Attempt at a Solution


I do think I have to use the lowest possible number no matter if it's an alkyl group or a halogen, can someone tell me if I'm correct. And the alphabetical order I am unsure of the reason why is because I am seeing an alkane named "2-methyl-4-chloro-5-bromononane" and this is not alphabetical.
 
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ok let me help you in understanding the rules ...first and most important rule is lowest number to the substituents ..in your example they have followed lowest sum rule ..you need not to worry about the alphabets
Next question is where I need to worry for alphabets :
let me help you with example
I CH2CH2CH2Cl
now in this case there is a tie ..both substituents can get the lowest same number ...in this case alphabetically Chloro will the get the highest priority .
 
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chemtopper said:
ok let me help you in understanding the rules ...first and most important rule is lowest number to the substituents ..in your example they have followed lowest sum rule ..you need not to worry about the alphabets
Next question is where I need to worry for alphabets :
let me help you with example
I CH2CH2CH2Cl
now in this case there is a tie ..both substituents can get the lowest same number ...in this case alphabetically Chloro will the get the highest priority .
Okay thanks for the help.
 

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