Calculating Mass of Precipitated Silver Bromate - Chemistry Homework

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Discussion Overview

The discussion revolves around a chemistry homework problem involving the calculation of the mass of precipitated silver bromate from a reaction between silver nitrate and potassium bromate in water. The focus includes the application of stoichiometry and considerations of solubility.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant presents a method for calculating the mass of silver bromate formed, concluding that the limiting reactant is potassium bromate, leading to a mass of 0.668 g of AgBrO3.
  • Another participant agrees with the method and states that the significant figures should be three.
  • A different participant introduces the concept of solubility, suggesting that after a certain mass of AgBrO3 precipitates, the solution may become saturated, questioning the assumption of complete insolubility of AgBrO3.
  • Another response confirms the calculation method and presents the answer in scientific notation as 6.68e-1 g.

Areas of Agreement / Disagreement

There is some agreement on the calculation method and the significant figures, but there is disagreement regarding the solubility of silver bromate and its implications for the calculation.

Contextual Notes

The discussion does not resolve the assumptions regarding the solubility of AgBrO3 and its effect on the precipitate mass calculation.

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Homework Statement


0.790 g of silver nitrate and 0.473 g of potassium bromate are added to 379 mL water. Solid silver bromate is formed, dried, and weighed. What is the mas in g of the precipitated silver bromate?


Homework Equations


AgNO3 + KBrO3 --> AgBrO3 + KNO3

AgNO3 = 169.87 g
KBrO3 = 197.00 g
AgBrO3 = 235.776 g
KNO3 = 101.10 g


The Attempt at a Solution



169.87g AgNO3 => 235.78g AgBrO3
0.790g AgNO3 => (235.78g AgBrO3/ 169.87g AgNO3) * 0.790g AgNO3= 1.0965 g AgBrO3

167.005 KBrO3 => 235.78g AgBrO3
0.473g KBrO3=> (235.78g AgBrO3/167.005 KBrO3)*0.473g KBrO3 = 0.668 g AgBrO3

Limiting Reactant is KBrO3, thus the answer would be 0.668 g AgBrO3, also how many significant figures should we use?
 
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Method seems fine , the significant figures should be 3.
 
Kso = 10-4.3 or something close to that number. That means that after 0.214g of AgBrO3 precipitates solution becomes saturated.

Unless what you wrote on chemicalforums is true, and you have to assume AgBrO3 is completely insoluble...
 
That method worked for me as well. Answer would be 6.68e-1
 

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