Cl2 + KI Reactions: Observing Changes Over Time

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SUMMARY

The discussion focuses on the reactions of chlorine gas (Cl2) and bromine monochloride (BrCl) with aqueous potassium iodide (KI). Initially, when Cl2 is bubbled through KI, the solution turns yellow/brown due to the formation of iodine (I2). After several minutes, a black/grey solid forms, indicating the presence of iodine precipitate rather than iodine gas. The participants also inquire about the reaction conditions and whether both Cl2 and BrCl are reacting in the same beaker.

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Homework Statement


Cl2 and BrCl each react with aqueous KI.
(i) Describe what would be seen when Cl2 is bubbled through aqueous KI for several minutes.
initially :
after several minutes :


Homework Equations

The Attempt at a Solution


I thought initially Cl2 would get decolourised, so the green/pale yellow colour fades
And after several minutes, a purple vapour would form (I2)
 
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Is what you have thought wrong? I see no trouble in it, unless the rate of reaction was too slow that nothing happened while you kept waiting.
 
CrazyNinja said:
Is what you have thought wrong? I see no trouble in it, unless the rate of reaction was too slow that nothing happened while you kept waiting.
CrazyNinja said:
Is what you have thought wrong? I see no trouble in it, unless the rate of reaction was too slow that nothing happened while you kept waiting.
The answer is:
initially: the solution turns yellow/brown
finally: black/grey solid forms.
I though iodine gas would form, not solid.
 
Two questions:
1) Are both Cl2 and BrCl reacting with KI in different beakers or the same one?
2) Are the reaction conditions given?
 
CrazyNinja said:
Two questions:
1) Are both Cl2 and BrCl reacting with KI in different beakers or the same one?
2) Are the reaction conditions given?
I think they are reacting in one beaker and there are no reaction conditions given.
 
I am really not sure what happens. Could it be that another inter-halogen compound forms?
 
CrazyNinja said:
I am really not sure what happens. Could it be that another inter-halogen compound forms?
I've no idea, they haven't provided a reaction.
 

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