Cl2 + KI Reactions: Observing Changes Over Time

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Discussion Overview

The discussion revolves around the reactions of chlorine (Cl2) and bromine monochloride (BrCl) with aqueous potassium iodide (KI), focusing on the observable changes over time. Participants explore the initial and final states of the reaction, considering both theoretical predictions and experimental observations.

Discussion Character

  • Homework-related
  • Exploratory
  • Debate/contested

Main Points Raised

  • One participant suggests that Cl2 would initially decolorize the solution, leading to a fading green/pale yellow color, and later produce purple vapor (I2).
  • Another participant challenges this view, indicating that the solution would turn yellow/brown initially and that a black/grey solid would form eventually, questioning the formation of iodine gas.
  • Several participants inquire about the experimental setup, specifically whether Cl2 and BrCl are reacting in the same beaker and if any specific reaction conditions are provided.
  • One participant expresses uncertainty about the reaction outcomes, proposing the possibility of another inter-halogen compound forming.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the observable changes during the reactions, with multiple competing views on the initial and final states of the solution and the nature of the products formed.

Contextual Notes

Participants note the lack of specific reaction conditions and the absence of a clear reaction equation, which may affect their interpretations and predictions.

Priyadarshini
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Homework Statement


Cl2 and BrCl each react with aqueous KI.
(i) Describe what would be seen when Cl2 is bubbled through aqueous KI for several minutes.
initially :
after several minutes :


Homework Equations

The Attempt at a Solution


I thought initially Cl2 would get decolourised, so the green/pale yellow colour fades
And after several minutes, a purple vapour would form (I2)
 
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Is what you have thought wrong? I see no trouble in it, unless the rate of reaction was too slow that nothing happened while you kept waiting.
 
CrazyNinja said:
Is what you have thought wrong? I see no trouble in it, unless the rate of reaction was too slow that nothing happened while you kept waiting.
CrazyNinja said:
Is what you have thought wrong? I see no trouble in it, unless the rate of reaction was too slow that nothing happened while you kept waiting.
The answer is:
initially: the solution turns yellow/brown
finally: black/grey solid forms.
I though iodine gas would form, not solid.
 
Two questions:
1) Are both Cl2 and BrCl reacting with KI in different beakers or the same one?
2) Are the reaction conditions given?
 
CrazyNinja said:
Two questions:
1) Are both Cl2 and BrCl reacting with KI in different beakers or the same one?
2) Are the reaction conditions given?
I think they are reacting in one beaker and there are no reaction conditions given.
 
I am really not sure what happens. Could it be that another inter-halogen compound forms?
 
CrazyNinja said:
I am really not sure what happens. Could it be that another inter-halogen compound forms?
I've no idea, they haven't provided a reaction.
 

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