Doping Rutile TiO2 with Quantum ESPRESSO v5.0.1

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  • Thread starter Thread starter Arun Prasath
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SUMMARY

The forum discussion centers on doping rutile TiO2 using Quantum ESPRESSO v5.0.1, specifically by substituting a nitrogen atom for a titanium atom. Users reported that the nitrogen atom did not form bonds with nearby atoms when visualized in XCRYSDEN. The issue arises from XCRYSDEN's bond visualization, which relies on predefined atomic types and distances rather than the actual physical interactions in the system. Adjusting the bond parameters in XCRYSDEN can resolve the visualization issue without affecting the underlying physics.

PREREQUISITES
  • Familiarity with Density Functional Theory (DFT) calculations
  • Understanding of Quantum ESPRESSO v5.0.1 functionalities
  • Knowledge of rutile TiO2 crystal structure
  • Experience with XCRYSDEN software for crystal visualization
NEXT STEPS
  • Explore advanced doping techniques in Quantum ESPRESSO
  • Learn how to modify bond parameters in XCRYSDEN
  • Investigate the effects of nitrogen doping on the electronic properties of TiO2
  • Study the visualization capabilities of other software tools like VESTA or OVITO
USEFUL FOR

Researchers and materials scientists working on semiconductor doping, computational chemists performing DFT calculations, and anyone utilizing Quantum ESPRESSO and XCRYSDEN for crystal structure analysis.

Arun Prasath
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Hi I am using Quantum ESPRESSO v5.0.1 for my dft calcultaions. For doping in rutile tio2, I have replaced a nitrogen atom in the position of Ti atom. But when I view the input structure through xcrysden software, the nitrogen atom didnt form any bonds with the near by atoms. What could be the problem? And how it could be overcomed? Thank You in advance...
 
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IIRC xcrysden draws bonds based on atomic types and distances. These are defined in a table in xcrysden and you can change it manually in the menu. It has nothing to do with the physics of the system.
 

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