Enthalpy of Reaction: Fe2O3 + CO --> CO2 + 2Fe3O4

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SUMMARY

The discussion focuses on calculating the enthalpy change (DeltaH) for the reaction Fe2O3 + CO --> CO2 + 2Fe3O4 using Hess's Law. The provided reactions are Fe2O3 + 3CO ---> 2Fe + 3CO2 with DeltaH = -28.0 kJ and 3Fe + 4CO2 ---> 4CO + Fe3O4 with DeltaH = 12.5 kJ. Participants emphasize the importance of balancing the compounds correctly and suggest using simple multiplication of the given equations to derive the desired reaction's enthalpy change. The correct approach involves manipulating the coefficients of the initial reactions rather than switching the equations around.

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  • Understanding of Hess's Law for calculating enthalpy changes
  • Knowledge of balancing chemical equations
  • Familiarity with enthalpy notation (DeltaH)
  • Basic concepts of thermodynamics related to chemical reactions
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Faiien
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Homework Statement


Given the following reactions

Fe2O3 + 3CO ---> 2Fe + 3CO2 DeltaH = -28.0kJ
3Fe + 4CO2 ---> 4CO + Fe3O4 DeltaH = 12.5kJ

the enthalpy of the reactions of Fe2O3 with CO
3Fe2O3 + CO ---> CO2 +2Fe3O4
what is DeltaH for this equation? ________ kJ

Homework Equations


DeltaH = H(products) - H(reactants)

The Attempt at a Solution


I've tried to switch the equations around to isolate certain solutions but I've had no luck at all, I would really appreciate some help on this problem.
 
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Well, start with something that's only in one equation and balance that. I'd recommend starting with balancing Fe2O3. Note: NOT Fe and O, but balance the compound. Treat the compound as an individual atom. Then do the same for a compound that's only in the other equation and balance that. Then work from there.
 
Could you offer more assistance, I still don't really understand what to do.
 
Well, first let me tell you that you don't need to switch around the equations at all. Simple multiplication will work in this case.

That said, what do you need to multiply the first equation, with one Ferric Oxide, to get the third equation, with three Ferric Oxides?

Same process with the other equation.
 

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