Explain in fragmented way 1-methylstyrene's spectrum

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1. Explain in fragmented way 1-methylstyrene's spectrum
2. Explain the gaseous and solid state PCl5 from IR and Raman spectra.

Any help related to these two questions i would be happy, i want to study all about these 2 questions.Material(text,texbook) or explanation,anything.
 

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