How to understand this acidic oxide chemical reaction?

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Discussion Overview

The discussion revolves around understanding a chemical reaction involving an acidic oxide in an aqueous solution, particularly focusing on the interaction between hydroxide ions and carbon dioxide, leading to the formation of carbonic acid. The scope includes theoretical aspects and potential mechanisms of the reaction.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification

Main Points Raised

  • One participant suggests that hydroxide ions act as both a Lewis base and a Brønsted acid in the presence of carbon dioxide, leading to a reaction that is not fully understood.
  • The participant questions how the oxygen anion interacts with carbon and the fate of the double bond with another oxygen in the reaction.
  • There is uncertainty about the source of protons that may attach to the oxygens in the formation of carbonic acid.
  • Another participant notes that inorganic chemistry typically does not focus on reaction mechanisms, contrasting it with organic chemistry.
  • It is mentioned that quantum mechanical calculations indicate that carbonic acid (H2CO3) is extremely unstable and its presence in aqueous solutions may be questionable.
  • A clarification is provided regarding the term "orgo," which refers to organic chemistry.

Areas of Agreement / Disagreement

Participants express differing views on the stability of carbonic acid and the mechanisms involved in the reaction, indicating that multiple competing perspectives remain without consensus.

Contextual Notes

There are limitations regarding the clarity of the reaction mechanisms and the stability of intermediates like carbonic acid, which are not fully resolved in the discussion.

zenterix
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Homework Statement
How exactly does the chemical reaction

$$\mathrm{CO_2+2OH^-\leftrightharpoons HCO_3^-+OH^-\leftrightharpoons CO_3^{2-}+H_2O}\tag{1}$$

happen?
Relevant Equations
I am learning about what an acidic oxide is and this example is given in Wikipedia.
The way I understand it is that we have an aqueous solution of something that produces hydroxide ions.

If there are carbon dioxide gas molecules in the solution then from the book I am reading it seems that the following definitely happens

1) One hydroxide acts as a Lewis base (donates electron pair to ##\mathrm{CO_2}## and also acts as a Bronsted acid (donates a proton) to another hydroxide.

1732470571100.png


The end result seems to be

1732470613033.png


though I am not sure exactly what is happening here.

For example, how exactly did the oxygen anion attach to the carbon and what happened to the double bond with the other oxygen?

2) So it seems we need to get from the last picture above to ##\mathrm{H_2CO_3}##.

This seems to result from two protons attaching to the oxygens with negative charge.

1732470971236.png


Do the protons come from water molecules?

In equation (1), the ##\mathrm{H_2CO_3}## is not explicitly stated. Why?
 
Last edited:
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Inorganic chemistry very rarely deals with mechanisms (which is a standard approach in orgo). That's just the way it is, so don't be surprised you can't find anything.

As far as I remember QM calculations suggest H2CO3 is extremely unstable (and its decomposition is catalyzed by water), so its presence in water solutions is dubious.
 
Borek said:
which is a standard approach in orgo
What is "orgo"?
 
zenterix said:
What is "orgo"?
Organic chemistry.
 

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